Carbon Storage News & Publications
News
October 19, 2022
Converting Carbon Dioxide to Minerals Underground
August 15, 2022
An Update to Award-Winning Carbon Storage Sensor Software
June 27, 2022
Capturing, Utilizing, and Storing Carbon with Solvents: Outlining a Path Forward
November 22, 2021
1st-of-a-Kind Project May Lead to Global Greenhouse Solutions
July 12, 2021
Bacon Joins Greenhouse Gas Control Editorial Board
February 1, 2017
PFLOTRAN-E4D: A parallel open source PFLOTRAN module for simulating time-lapse electrical resistivity data
January 15, 2020
PNNL Fracturing Fluid: Cost-effective Option for Geothermal Energy
November 13, 2019
Where Liquid Meets Air: Unearthing How Air Pollutants Form
February 6, 2019
Tracking Injected Fluids: A Seismic Contrast Agent Breakthrough
November 4, 2016
PNNL Wins 2 R&D 100 Awards for Underground Cleanup, Carbon Capture
Publications
SEPTEMBER 28, 2022
Journal Article
Molecular-Scale Mechanisms of CO2 Mineralization in Nanoscale Interfacial Water Films
JULY 22, 2019
Conference Paper
Geophysical Monitoring with Seismic Metamaterial Contrast Agents
JUNE 18, 2019
Journal Article
Anomalously low activation energy of nanoconfined MgCO3 precipitation
AUGUST 13, 2019
Journal Article
Quantitative Review of Olivine Carbonation Kinetics: Reactivity Trends, Mechanistic Insights, and Research Frontiers
MAY 23, 2019
Journal Article
Surface-Catalyzed Oxygen Exchange during Mineral Carbonation in Nanoscale Water Films
SEPTEMBER 6, 2018
Book Chapter
Experimental studies of reactivity and transformations of rocks and minerals in water-bearing supercritical CO2
DECEMBER 26, 2018
Journal Article
Microporous and Flexible Framework Acoustic Metamaterials for Sound Attenuation and Contrast Agent Applications
SEPTEMBER 6, 2018
Journal Article
Water Structure Controls Carbonic Acid Formation in Adsorbed Water Films
FEBRUARY 27, 2018
Journal Article
CO2 Mineral Sequestration in Naturally Porous Basalt
SEPTEMBER 6, 2018
Journal Article
Water Structure Controls Carbonic Acid Formation in Adsorbed Water Films
JANUARY 10, 2017
Journal Article
Field Validation of Supercritical CO2 Reactivity with Basalts
OCTOBER 25, 2017
Journal Article
Tipping Point for Expansion of Layered Aluminosilicates in Weakly Polar Solvents: Supercritical CO2
JULY 3, 2017
Journal Article
Wallula Basalt Pilot Demonstration Project: Post-Injection Results and Conclusions
JANUARY 12, 2017
Journal Article
Role of Cations in CO2 Adsorption, Dynamics, and Hydration in Smectite Clays Under in situ Supercritical CO2 Conditions
NOVEMBER 9, 2015
Journal Article
CO2 Storage by Sorption on Organic Matter and Clay in Gas Shale
JULY 15, 2015
Journal Article
Competitive Sorption of CO2 and H2O in 2:1 Layer Phyllosilicates
JUNE 16, 2015
Journal Article
Evidence for Carbonate Surface Complexation during Forsterite Carbonation in Wet Supercritical Carbon Dioxide
APRIL 7, 2015
Journal Article
Impacts of Organic Ligands on Forsterite Reactivity in Supercritical CO2 Fluids
DECEMBER 1, 2014
Journal Article
Anomalous porosity preservation and preferential accumulation of gas hydrate in the Andaman accretionary wedge, NGHP-01 site 17A
FEBRUARY 11, 2014
Journal Article
Surface Condensation of CO2 onto Kaolinite
MAY 1, 2014
Journal Article
Mineralization of Basalts in the CO2-H2O-SO2-O2 System
JULY 1, 2013
Journal Article
Insights into Silicate Carbonation Processes in Water-Bearing Supercritical CO2 Fluids
JANUARY 25, 2013
Journal Article
Near-Infrared Spectroscopic Investigation of Water in Supercritical CO2 and the Effect of CaCl2
AUGUST 1, 2013
Journal Article
Mineralization of Basalts in the CO2-H2O-H2S System
AUGUST 5, 2013
Journal Article
Clay hydration/dehydration in dry to water-saturated supercritical CO2: Implications for caprock integrity
SEPTEMBER 1, 2012
Journal Article
Molecular interactions of SO2 with carbonate minerals under co-sequestration conditions: a combined experimental and theoretical study
APRIL 3, 2012
Journal Article
In Situ X-Ray Diffraction Study of Na+ Saturated Montmorillonite Exposed to Variably Wet Super Critical CO2
APRIL 25, 2012
Journal Article
In Situ Molecular Spectroscopic Evidence for CO2 Intercalation into Montmorillonite in Supercritical Carbon Dioxide
AUGUST 1, 2012
Journal Article
Reaction of Water-Saturated Supercritical CO2 with Forsterite: Evidence for Magnesite Formation at Low Temperatures
APRIL 25, 2012
Journal Article
In Situ Infrared Spectroscopic Study of Brucite Carbonation in Dry to Water-Saturated Supercritical Carbon Dioxide
JULY 19, 2011
Journal Article
In Situ Infrared Spectroscopic Study of Forsterite Carbonation in Wet Supercritical CO2
APRIL 1, 2011
Journal Article
Basalt Reactivity Variability with Reservoir Depth in Supercritical CO2 and Aqueous Phases
APRIL 1, 2011
Journal Article
Multiphase Sequestration Geochemistry: Model for Mineral Carbonation
FEBRUARY 1, 2009
Journal Article
Water Reactivity in the Liquid and Supercritical CO2 Phase: Has Half the Story Been Neglected?
- Miller, QRS*, JP Kaszuba, HT Schaef, SN Kerisit, ME Bowden, BP McGrail, KM Rosso. 2020. "Emerging Investigator Series: Ion Diffusivities in Nanoconfined Interfacial Water Films Contribute to Mineral Carbonation Thresholds." Environmental Science: Nano, 2020, 7, 1068. https://doi.org/10.1039/C9EN01382B
- Bowers, GM, HT Schaef, QRS Miller, ED Walter, SD Burton, DW Hoyt, and JA Horner, et al. 2019. "C13 Nuclear Magnetic Resonance Spectroscopy of Methane and Carbon Dioxide in a Natural Shale." ACS Earth and Space Chemistry 3, no. 3:324–328.
- Qafoku, O, ES Ilton, ME Bowden, L Kovarik, X Zhang, RK Kukkadapu, and MH Engelhard, CJ Thompson, H.T. Schaef et. al., 2018. "Synthesis of Nanometer-Sized Fayalite and Magnesium-Iron(II) Mixture Olivines." Journal of Colloid and Interface Science 515.
- Miller, QRS, HT Schaef, J Kaszuba, L Qiu, ME Bowden, BP McGrail, and QRS Miller. 2018. "Tunable manipulation of mineral carbonation kinetics in nanoscale water films via citrate additives." ES&T 52, no. 12:7138-7148.
- Loring, JS, DH Bacon, RD Springer, A Anderko, S Gopinath, CM Yonkfonski, CJ Thompson, BP McGrail, KM Rosso, and HT Schaef. 2017. "Water Solubility at Saturation for CO2-CH4 Mixtures at 50 °C and 90 bar." Journal of Chemical & Engineering Data, 62, (5), 1608-1614.
- Schaef, HT, SK Nune, CE Strickland, KW Jung, PF Martin, JS Loring, BP McGrail. 2016. "Injectable Contrast Agents for Enhanced Subsurface Mapping and Monitoring." Energy Procedia 114 (2017) 3764–3770.
- Bacon, DH, CM Ruprecht, HT Schaef, MD White, BP McGrail. 2015. “CO2 Storage by Adsorption on Organic Matter and Clay in Gas Shale.” Journal of Unconventional Oil and Gas Resources, V12, pages 123-133.
- Qafoku, O, DA Dixon, KM Rosso, HT Schaef, ME Bowden, BW Arey and AR Felmy. 2015. "Dynamics of Magnesite Formation at Low Temperature and High pCO2 in Aqueous Solution." ES&T, 49(17): 10736-10744.
- Loring, JS, ES Ilton, J Chen, CJ Thompson, PF Martin, P Bénézeth, KM Rosso, AR Felmy, and HT Schaef. 2014. "In Situ Study of CO2 and H2O Partitioning between Na–Montmorillonite and Variably Wet Supercritical Carbon Dioxide." Langmuir, 30(21): 6120-6128.
- Schaef, HT, QRS Miller, CJ Thompson, JS Loring, MS Bowden, BW Arey, BP McGrail, KM Rosso. 2013. “Silicate Carbonation in Supercritical CO2 Containing Dissolved H2O: an in situ High Pressure X-Ray Diffraction and Infrared Spectroscopy Study.” Energy Procedia, Vol 37, 5892-5896.
- Rother, G, ES Ilton, D Wallacher, T Hauss, HT Schaef, O Qafoku, KM Rosso, AR Felmy, EG Krukowski, AG Stack, et al. 2013. "CO2 Adsorption to Sub-Single Hydration Layer Montmorillonite Clay Studied by Excess Sorption and Neutron Diffraction." ES&T, 47 (1) pp. 205-211.
- Windisch, CF, Jr, HT Schaef, PF Martin, AT Owen, and BP McGrail. 2012. "Following O-18 uptake in scCO2-H2O mixtures with Raman spectroscopy." Spectrochimica Acta Part a-Molecular and Biomolecular Spectroscopy 94: 186-191.
- Schaef, HT, CF Windisch, Jr., BP McGrail, PF Martin, and KM Rosso. 2011. "Brucite Mg(OH)2carbonation in wet supercritical CO2: An in situ high pressure X-ray diffraction study." Geochimica et Cosmochimica Acta 75(23).
- Windisch, CF Jr; V Glezakou, P Martin, BP McGrail, and HT Schaef, 2011. “Transposition of the Fermi Dyad in CO2 by Labeled Oxygens.” Journal of Physical Chemistry B, (submitted July, 2011).
- Schaef, HT, ES Ilton, OQafoku, PF Martin, AR Felmy, and KM Rosso, 2011. “In situ XRD Study of Ca2+ Saturated Montmorillonite (STX-1) Exposed to Anhydrous scCO2.” International Journal of Greenhouse Gas Control, submitted (submitted June, 2011).
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