PNNL researchers worked to decouple the effects that solvents impose on reactions catalyzed in the liquid phase.

New research finds that reaction rates for cyclic alcohol dehydration increase as ionic strength increases, independent of reaction mechanism.

Soil moisture influences both the activity of soil DNA viruses, as well as the composition and abundance of RNA viruses.

A new microbial community model reveals previous exposure to hydrologic variation influences a species’ specialized biogeochemical functions.

Detailed characterization of molecules in, under, and along the Columbia River reveal potential mechanisms for biogeochemical cycling.

Integrating hydrogeology and biogeochemistry are required to model the dynamics of geochemical processes occurring in river corridor zones where groundwater and surface water mix.

Theoretical analysis reveals flow variations that happen over longer time periods affect a plume’s spread and center of mass.

Knowing which bacteria in a community are involved with carbon cycling could help scientists predict how microbial carbon storage and release could influence future climate dynamics.

Local ionic strength within zeolite pores tailors the chemical potential of reacting molecules, leading to high cyclohexanol dehydration activity

Research shows that previous drought and flooding conditions strongly influence soil respiration and carbon composition.

Principles derived from coastal wetlands to describe wetland channel cross-sections were applicable to the Columbia River estuary, but not the tidal river.

Tetranuclear molybdenum sulfide clusters encaged in zeolites mimic the FeMo-cofactor of nitrogenase, offering a new opportunity for improving industrial hydrotreatment processes.

New research uncovers the mechanism of carbon dioxide reduction by metal-O-Fe bonds of single-metal atoms and metal nanoparticles supported by oxidic surfaces.

Understanding the fundamental relationships between river flow, water exchange, and nutrient cycling can inform ecosystem effects of river regulation.

Characterizing the electron redistribution that allows the binding of molecular nitrogen to the catalytic core of nitrogenase.

A new approach uses CO₂ to favorably co-produce methanol and glycols in a simple one-pot reaction.

Variability in field measurement conditions likely does not impact estimates of an important flux in the global carbon cycle.

Researchers propose and test foundational concepts for the new subdiscipline of “meta-metabolome ecology.”

Microbiome and soil chemistry characterization at long-term bioenergy research sites challenges idea that switchgrass increases carbon accrual in surface soils of marginal lands.

New biogeochemical modeling uses high-resolution mass spectrometry data to reveal how organic matter thermodynamics affect ecosystems across scales.