Research provided definitive spectroscopic characterization, reactivity, and deactivation of a reactive monomeric diphosphine-copper hydride intermediate.

Developed a method for selectively anchoring diverse divalent metal cations in zeolites, important for precise control over catalytic materials.

Developed a simple kinetic framework for evaluating catalyst hydride transfer ability.

PNNL has formed a partnership with the Orlando-based firm Refinity, which has licensed a key process from PNNL that will help the company convert mixed plastic waste into valuable industrial products like chemicals, plastics, and fuels.

Novel Applications for Synchronized Power Instrumentation seeks to improve electric grid resilience, reliability, security, and affordability.

A low-temperature, single-stage catalytic process converts PVC and polyolefin into valuable alkanes.

A comprehensive investigation provides quantitative data on the interaction between zeolite pores and linear alcohols, with hydroxyl group interactions playing the largest role.

After isolating copper hydride monomers, researchers identified the mechanistic details of catalyst aggregation and cluster formation.

The low-temperature breakdown of polyolefins is driven by carbenium ions generated from chloroaluminate ionic liquids.

PNNL chemical engineer Mariefel Olarte shares passion for mentoring students and the next-generation workforce.

PNNL's accomplishments in FY 2024 help address the remaining challenges the wind industry faces.

Tuning the environment of supported palladium atoms with hydrogen treatment enhances their catalytic activity.

A switchable single-atom catalyst is activated in the presence of surface intermediates and reverts to its stable inactive form when the reaction is completed.

Increasing the concentration of ions in zeolite micropores leads to a significant increase in the rate of acid catalyzed reactions.

Electronic modifications from hydrogen spillover onto the oxide support increase the activity of single-atom rhodium catalysts.

With the launch of a large research barge, PNNL and collaborators took another significant step to improve offshore wind forecasting that will lower risk and cost associated with offshore wind energy development.

ChemReasoner combines decades of chemistry knowledge with large language models to propose strategies for effective new catalysts.

Catalysts that efficiently transfer hydrogen for storage in organic hydrogen carriers are key for more sustainable generation and use of hydrogen. New research identifies activity descriptors that can accelerate novel catalyst development.

The nation is closer to its offshore wind energy goals than ever before, but better wind forecasting is still needed. To address this challenge, PNNL and collaborators are charting a new course with help from novel technology.

PNNL is one of the founding partners of the Trillion Parameter Consortium, which was formed to create reliable generative AI models.