The thermal decomposition of chromium hexamine chloride in both helium and ammonia gas has been investigated by thermogravimmetric and differential thermal analysis (TGA and DTA) and intermediate reaction products have been examined via Fourier transform infared spectroscopy and powder X-ray diffraction in an effort to understand how ammonolyis of this nitride precursor takes place.
Revised: November 29, 2010 |
Published: January 1, 2008
Citation
Weil K.S. 2008.The Synthesis of Transition Metal Nitrides via Thermolysis of Metal-Ammine Complexes: Part 1. Chromium Nitride.Journal of Solid State Chemistry 181, no. 1:199-210.PNNL-SA-46326.doi:10.1016/j.jssc.2007.11.008