A new set of pyridine and pyridine N-oxides functionalized with N,N-dimethylpropionamide pendant groups in the 2- and 2,6-positions have been prepared from the combination of 2-chloromethylpyridine and 2,6-bis(chloromethyl) pyridine with ?-lithio N,N-dimethyl acetamide. The coordination interaction between 2-(N,N-dimethylpropionamide) pyridine N-oxide (10) and Tb(NO3)3 has been unambiguously defined via single crystal X-ray diffraction analysis of Tb(10)(NO3)3(H2O). Battelle operates PNNL for the USDOE
Revised: May 2, 2007 |
Published: February 1, 2007
Citation
Binyamin I., S. Pailloux, B.P. Hay, B.M. Rapko, E.N. Duesler, and R.T. Paine. 2007.Synthesis of Propionamide Pyridine and Pyridine N-oxide Ligands.Journal of Heterocyclic Chemistry 44, no. 1:99-103.PNNL-SA-49118.