A “bare” V5+ complex with glutaroimide-dioxime (H3L), a ligand for uranium recovery from seawater, was synthesized from aqueous solution as Na[V(L)2]2H2O and the structure determined by x-ray diffraction. It is the first non-oxo V(V) complex that has been directly synthesized in and crystallized from aqueous solution.
Revised: December 15, 2016 |
Published: April 1, 2016
Citation
Leggett C.J., B.F. Parker, S.J. Teat, Z. Zhang, P.D. Dau, W.W. Lukens, and S.M. Peterson, et al. 2016.Structural and spectroscopic studies of a rare non-oxido V(v) complex crystallized from aqueous solution.Chemical Science 7, no. 4:2775-2786.PNNL-SA-112588.doi:10.1039/c5sc03958d