August 7, 2003
Journal Article

On the Relationship between the Enthalpy of Formation of Carbenes upon Cleavage of the Double Bond in Fluoroolefins and the Electron Density on the pi Bond: An Ab Initio Study

Abstract

In this study, we established a correlation between the enthalpy (????of cleavage of the C=C bond in fluorine-substituted olefins giving rise to two carbenes in the electronic ground state and the distribution of the electron density on this bond.

Revised: January 24, 2007 | Published: August 7, 2003

Citation

Borisov Y.A., B.C. Garrett, Y.A. Kobanovskii, I.V. Bilera, and N.N. Buravtsev. 2003. On the Relationship between the Enthalpy of Formation of Carbenes upon Cleavage of the Double Bond in Fluoroolefins and the Electron Density on the pi Bond: An Ab Initio Study. Doklady. Physical Chemistry 392, no. 1-3:212-216. PNNL-SA-43744. doi:10.1023/A:1025778018991