January 27, 2015
Journal Article

Observation Of Electron-beam-induced Phase Evolution Mimicking The Effect Of Charge-discharge Cycle In Li-rich Layered Cathode Materials Used For Li-ion Batteries

Abstract

Capacity loss, and voltage fade upon electrochemical charge-discharge cycling observed in lithium-rich layered cathode oxides (Li[LixMnyTM1-x-y]O2 , TM = Ni, Co or Fe) have recently been identified to be correlated to the gradual phase transformation, featuring the formation of a surface reconstructed layer (SRL) that evolves from a thin (

Revised: March 6, 2020 | Published: January 27, 2015

Citation

Lu P., P. Yan, E. Romero, E.D. Spoerke, J. Zhang, and C.M. Wang. 2015. Observation Of Electron-beam-induced Phase Evolution Mimicking The Effect Of Charge-discharge Cycle In Li-rich Layered Cathode Materials Used For Li-ion Batteries. Chemistry of Materials 27, no. 4:1375-1380. PNNL-SA-107668. doi:10.1021/cm5045573