September 29, 2014
Journal Article

Molecular Genetic Characterization of Terreic Acid Pathway in Aspergillus terreus

Abstract

Terreic acid is a natural product derived from 6-methylsalicylic acid (6-MSA). A compact gene cluster for its biosynthesis was characterized. Isolation of the intermediates and shunt products from the mutant strains, in combined with bioinformatic analyses, allowed us to propose a biosynthetic pathway for terreic acid. Defining the pathway and the genes involved will facilitate the engineering of this molecule with interesting antimicrobial and antitumor bioactivities.

Revised: January 20, 2015 | Published: September 29, 2014

Citation

Guo C., W. Sun, K.S. Bruno, and C.C. Wang. 2014. Molecular Genetic Characterization of Terreic Acid Pathway in Aspergillus terreus. Organic Letters 16, no. 20:5250–5253. PNNL-SA-102991. doi:10.1021/ol502242a