Two dimensional layered like coordination polymer [Co(2,4'-bpdc)(H2O)]n containing one-dimensional double-stranded left-handed helical channels from achiral building block 2,4'-biphenyldicarboxylic acid (2,4'-H2bpdc) was reported. The resultant crystals were not racemic as evidenced by the observation of strong signals in vibrational circular dichroism (VCD) and circular dichroism (CD) spectra
Revised: May 21, 2013 |
Published: July 1, 2011
Citation
Yi X.Y., H. Fang, Z. Gu, Z. Zhou, Y. Cai, J. Tian, and P.K. Thallapally. 2011.Metal-Organic Frameworks with Achiral/Monochiral Nano-channels.Crystal Growth & Design 11, no. 7:2824-2828.PNNL-SA-75152.doi:10.1021/cg101618n