Intensity of Cross-Peaks in HYSCORE Spectra of S=1/2, I=1/2 Spin Systems

June 1, 2000

Journal Article

Intensity of Cross-Peaks in HYSCORE Spectra of S=1/2, I=1/2 Spin Systems

Abstract

The cross-peak intensity for S=1/2, I=1/2 spin system in two-dimensional HYSCORE spectra of single-crystals and powders is analyzed. There is a fundamental difference between these two cases. For single crystals, the cross-peak intensity is distributed between the two (+,+) and (+,-) quadrants of the HYSCORE spectrum by the ratio c2:s2 (C. Gemperle, G. Aebli, A. Schweiger, R.R. Ernst, J. Magn. Reson. 88, 241 (1990)).

Revised: May 17, 2002 | Published: June 1, 2000

Citation

Dikanov S.A., A.M. Tyryshkin, and M.K. Bowman. 2000. Intensity of Cross-Peaks in HYSCORE Spectra of S=1/2, I=1/2 Spin Systems. Journal of Magnetic Resonance 144, no. 2:228-242. PNNL-SA-32587.