Oxygen diffusion and ionic conductivity of samaria-doped ceria (SDC) thin films have been studied as a function of composition using experiment and atomistic simulation. SDC thin films were grown on Al2O3 (0001) substrates by oxygen plasma-assisted molecular beam epitaxy (OPA-MBE) technique. The experimental results show a peak in electrical conductivity of SDC at 15 mol% Sm2O3. The oxygen diffusion coefficient obtained from molecular dynamics simulation of the same system shows a peak at about 13 mol% Sm2O3. The activation energy for oxygen diffusion was found to be in the range from 0.8 to 1.0 eV by simulations depending on the Sm2O3 content, which compares well with the range from 0.6 to 0.9 eV given by the experimental work. The simulations also show that oxygen vacancies prefer Sm3+ ions as first neighbors over Ce4+ ions. The present results reveal that the optimum samaria content for ionic conductivity in single crystals of SDC is less than that in polycrystals, which can be related to the preferential segregation of dopant cations to grain boundaries in polycrystals.
Revised: December 13, 2011 |
Published: December 12, 2011
Citation
Sanghavi R.P., R. Devanathan, M.I. Nandasiri, S.N. Kuchibhatla, L. Kovarik, S. Thevuthasan, and S. Prasad. 2011.Integrated experimental and modeling study of the ionic conductivity of samaria-doped ceria thin films.Solid State Ionics 204-205.PNNL-SA-76714.doi:10.1016/j.ssi.2011.10.007