March 3, 2010
Journal Article

Gas-Induced Expansion and Contraction of a Fluorinated Metal-Organic Framework

Abstract

Synthesis and gas sorption properties of a novel fluorinated MOF using the commercially available 2,2-Bis(4-carboxyphenyl)hexafluoropropane is reported with high selectivity toward CO2, H2S, and SO2 as well as breathing motion upon solvent removal and gas inclusion

Revised: September 7, 2010 | Published: March 3, 2010

Citation

Fernandez C.A., P.K. Thallapally, R.K. Motkuri, S.K. Nune, J.C. Sumrak, J. Tian, and J. Liu. 2010. Gas-Induced Expansion and Contraction of a Fluorinated Metal-Organic Framework. Crystal Growth & Design 10, no. 3:1037-1039. PNNL-SA-68508. doi:10.1021/cg9014948