Photoelectron spectra of the title molecules are reported at 3.49 eV photon energy. Vibrational structures are resolved in the spectra of FeC-3 and FeC3H_. The feC4- spectrum is unusually broad, indicating a large equilibrium geometry change from the anion to the neutral states.
Revised: August 14, 2019 |
Published: February 15, 1995
Citation
Fan J., L. Lou, L. Lou, and L. Wang. 1995.FeC-n and FeCnH-(n=3,4): A photoelectron spectroscopic and density functional study.Journal of Chemical Physics 102, no. 7:2701-2707. PNL-SA-24618. doi:10.1063/1.468646