Unusual cleavage of P-C and C-H bonds of the P2N2 ligand in heteroleptic [Ni(P2N2)(diphosphine)]2+ complexes results in the formation of an iminium formyl nickelate featuring a C,P,P-tridentate coordination mode.
Revised: August 14, 2019 |
Published: July 4, 2016
Citation
Zhang S., H. Li, A.M. Appel, M.B. Hall, and R.M. Bullock. 2016.Facile P-C/C-H Bond-Cleavage Reactivity of Nickel Bis(diphosphine) Complexes.Chemistry - A European Journal 22, no. 28:9493–9497.PNNL-SA-115898.doi:10.1002/chem.201601469