Superior activity and selectivity of a Cu ion-exchanged SSZ-13 zeolite in the selective catalytic reduction (SCR) of NOx with NH3 were observed, in comparison to Cu-beta and Cu-ZSM-5 zeolites. Cu-SSZ-13 was not only more active in the NOx SCR reaction over the entire temperature range studied (up to 550 °C), but also more selective toward nitrogen formation, resulting in significantly lower amounts of NOx by-products (i.e., NO2 and N2O) than the other two zeolites. In addition, Cu-SSZ-13 demonstrated the highest activity and N2 formation selectivity in the oxidation of NH3. The results of this study strongly suggest that Cu-SSZ-13 is a promising candidate as a catalyst for NOx SCR with great potential in after-treatment systems for either mobile or stationary sources.
Revised: December 15, 2010 |
Published: October 21, 2010
Citation
Kwak J., R.G. Tonkyn, D. Kim, J. Szanyi, and C.H. Peden. 2010.Excellent activity and selectivity of Cu-SSZ-13 in the selective catalytic reduction of NOx with NH3.Journal of Catalysis 275, no. 2:187-190.PNNL-SA-73441.doi:10.1016/j.jcat.2010.07.031