Herein we report the ?rst example of a metal-organic framework (MOF) in which the location of Li+ ions trapped in the porous con?nement can be unambiguously de?ned by single-crystal X-ray di?raction. Furthermore, the Li+-doped MOF shows signi?cant enhancement in gas uptake as well as selective adsorption of CO2 over CH4.
Revised: December 3, 2020 |
Published: July 15, 2019
Citation
Han Y., K. Liu, M.A. Sinnwell, L. Liu, H. Huang, and P.K. Thallapally. 2019.Direct Observation of Li+ Ions Trapped in a Mg2+-Templated Metal- Organic Framework.Inorganic Chemistry 58, no. 14:8922-8926.PNNL-SA-147562.doi:10.1021/acs.inorgchem.9b01207