Two novel cadmium–organic frameworks containing achiral multiwalled helical nanotubular channels, [Cd(HImDC)(S)]n (S = Im(1) and Py(2)), have been synthesized and characterized using single crystal X-ray diffraction, in which 1 converts to 2 upon refluxing 1 in pyridine solution with noticeable porosity and hydrogen uptake at medium pressure.
Revised: August 3, 2010 |
Published: August 7, 2010
Citation
Gu Z., Y. Cai, H. Fang, Z. Zhou, P.K. Thallapally, J. Tian, and J. Liu, et al. 2010.Conversion of Nonporous Helical Cadmium Organic Famework to a Porous Form.Chemical Communications 46, no. 29:5373–5375.PNNL-SA-72526.