June 16, 2014
Journal Article

Arginine-Containing Ligands Enhance H-2 Oxidation Catalyst Performance

Abstract

In H2 fuel cells, performance depends on factors controlling turnover frequency and energy efficiency in the electrocatalytic oxidation of H2. Nature uses the hydrogenase enzymes to oxidize H2 at high turnover frequencies (up to 20,000 s-1) and low overpotentials (

Revised: September 30, 2014 | Published: June 16, 2014

Citation

Dutta A., J.A. Roberts, and W.J. Shaw. 2014. Arginine-Containing Ligands Enhance H-2 Oxidation Catalyst Performance. Angewandte Chemie International Edition 53, no. 25:6487-6491. PNNL-SA-100189. doi:10.1002/anie.201402304