The adsorption of CO on reduced, rutile TiO2(110) is investigated using IR reflection-absorption spectroscopy and temperature programmed desorption. Experiments using s- and p-polarized IR light incident along the [001] and ]011[ azimuths give detailed information on the adsorption geometry of the CO as a function of the CO coverage, ?CO. The results indicate that for 0
Revised: February 21, 2013 |
Published: December 6, 2012
Citation
Petrik N.G., and G.A. Kimmel. 2012.Adsorption geometry of CO versus coverage on TiO2(110) from s- and p-polarized infrared spectroscopy.The Journal of Physical Chemistry Letters 3, no. 23:3425-3430.PNNL-SA-90608.doi:10.1021/jz301413v