March 31, 2016
Report

Use of a Ca-Citrate-Phosphate Solution to Form Hydroxyapatite for Uranium Stabilization of Rifle Sediments: Laboratory Proof of Principle Studies

Abstract

The purpose of this laboratory scale study was to evaluate the effectiveness of a hydroxyapatite (Ca10(PO4)6(OH)2) permeable reactive barrier and source area treatment in Rifle sediments. Phosphate treatment impact was evaluated by comparing uranium leaching and surface phase changes in untreated to PO4-treated sediments. The impact of the amount of phosphate precipitation in the sediment on uranium mobility was evaluated with three different phosphate loadings. A range of flow velocity and uranium concentration conditions (i.e., uranium flux through the phosphate-treated sediment) was also evaluated to quantify the uranium uptake mass and rate by the phosphate precipitate.

Revised: April 3, 2018 | Published: March 31, 2016

Citation

Szecsody J.E., R.C. Moore, M.J. Rigali, V.R. Vermeul, and J. Luellen. 2016. Use of a Ca-Citrate-Phosphate Solution to Form Hydroxyapatite for Uranium Stabilization of Rifle Sediments: Laboratory Proof of Principle Studies Richland, WA: Pacific Northwest National Laboratory.