PNNL

Abstract

Scientific and technological innovations are needed to realize effective production of natural gas hydrates. Whereas global estimates of natural gas hydrate reservoirs are vast, accumulations vary greatly in nature and form. Suboceanic deposits vary from disperse concentrations residing at low saturations in the pore space of unconsolidated sediments of sand-sized particles to higher concentrations residing in the fractures of sediments of clay-sized particles. Conventional methods for gas hydrate production, include depressurization, thermal stimulation and inhibitor injection. For suboceanic accumulations in sandy sediments, depressurization has been shown, through numerical simulation, to be the most feasible production technology. However, recovery efficiencies are too low to justify pursuing these energy reservoirs. Under high pressure, low temperature suboceanic conditions the hydrate structure can accommodate small molecules other than methane (CH4), such as carbon dioxide (CO2) and nitrogen (N2) in both the small and large cages. Although CO2 and N2 clathrates generally are not naturally as abundant as those of CH4, their occurrence forms the foundation of an unconventional approach for producing natural gas hydrates that involves the exchange of CO2 with CH4 in the hydrate structure. This unconventional concept has several distinct benefits over the conventional methods: 1) the heat of formation of CO2 hydrate is greater than the heat of dissociation of CH4 hydrate, providing a low-grade heat source to support additional methane hydrate dissociation, 2) exchanging CO2 with CH4 will maintain the mechanical stability of the geologic formation, and 3) the process is environmentally friendly, providing a sequestration mechanism for the injected CO2. An operational mode of the STOMP simulator has been developed at the Pacific Northwest National Laboratory that solves the coupled flow and transport equations for the mixed CH4-CO2 hydrate system under nonisothermal conditions, with the option for considering NaCl as an inhibitor in the pore water. This paper describes the numerical simulator, its formulation, assumptions, and solution approach and demonstrates, via numerical simulation, the production of gas hydrates from suboceanic accumulations in low-saturation sandy sediments using the CO2-CH4 exchange technology.