PNNL

Abstract

XAFS measurements at both the M3,2 and L3,2 edges of Pt and Au as well as scanning electron microscopy studies have been carried out for a series of porous silicon specimens onto which fine particles of Au and Pt with nanometre and tens of nanometre dimensions have been dispersed. A wet chemistry technique developed in our laboratory was used for the deposition. The Au XAFS clearly show that the Au deposits are essentially Au metal while the Pt deposits exhibit features that are noticeably different from that of metallic Pt. The M3,2 and L3,2 the XANES and their implications are discussed.