May 4, 2020
Journal Article

Low-Pt-Content Ternary PdCuPt Nanodendrites: An Efficient Electrocatalyst for Oxygen Reduction Reaction

Shaofang Fu
Chengzhou Zhu
Junhua Song
Peina Zhang
Mark Engelhard
Haibing Xia
Dan Du

Abstract

Dendritic nanostructures are capturing increasing attentions in electrocatalysis owing to their unique structural features and low density. Herein, we report for the first time bromide ions mediated synthesis of low-Pt-content PdCuPt ternary nanodendrites via galvanic replacement reaction between Pt precursor and PdCu template in aqueous solution. The experimental results show that the ternary PdCuPt nanodendrites present enhanced electrocatalytic performance for oxygen reduction reaction in acid solution compared with commercial Pt/C as well as some state-of-the-art catalysts. In details, the mass activity of the PdCuPt catalyst with optimized composition is 1.73 A/mgPt at 0.85 V vs RHE, which is 14 times higher than that of commercial Pt/C catalyst. Moreover, the long-term stability test demonstrates its better durability in acid solution. After 5k cycles, there is still 70% electrochemical surface area maintained. This method provides an efficient way to synthesize trimetallic alloys with controllable composition and specific structure for oxygen reduction reaction.

Revised: May 4, 2020 | Published: January 21, 2017

Citation

Fu S., C. Zhu, J. Song, P. Zhang, M.H. Engelhard, H. Xia, and D. Du, et al. 2017. "Low-Pt-Content Ternary PdCuPt Nanodendrites: An Efficient Electrocatalyst for Oxygen Reduction Reaction." Nanoscale 9, no. 3:1279-1284. PNNL-SA-118667. doi:10.1039/c6nr06646a