A Laminar Flow Tube Reactor (LFTR) was used to study the nucleation of water vapor. Computational analysis was carried out to define the operating conditions of the LFTR suitable for water nucleation measurements. An interface between the LFTR and a mass spectrometer was developed to analyze the chemical content of the freshly nucleated water particles. Presence of contaminants was detected in the initial configuration of the LFTR. As a result, improvements were made to the LFTR to achieve ultra-high purity conditions in the system. The nucleation rate of water vapor as a function of supersaturation was measured over the temperature range 210-250 K. The first measurement of the nucleation rate of water at a temperature of 210 K was obtained. Reasonable agreement with the classical theory predictions is observed for temperatures in the range 230-250 K. However, below 220 K, classical theory begins to overestimate nucleation rates compared to experimental data and the disagreement grows with decreasing temperature. The experimental data obtained provide an excellent benchmark for further nucleation studies of binary, ternary and more complex systems.
Revised: November 20, 2003 |
Published: June 22, 2002
Citation
Mikheev V.B., P.M. Irving, N.S. Laulainen, S.E. Barlow, and V.V. Pervukhin. 2002.Laboratory Measurement of Water Nucleation Using a Laminar Flow Tube Reactor.Journal of Chemical Physics 116, no. 24:10,772-10,786.PNNL-SA-35630.