PNNL

Abstract

Copper oxide quantum dots (CuOQD) were grown in various thicknesses on different SrTiO3(001) surfaces and were investigated by near edge x-ray absorption fine structure (NEXAFS) spectroscopy. The experimental growth conditions for the CuOQD were optimized to obtain Cu2O as the major phase. The CuOQD grown on clean SrTiO3(001) surfaces at 825 K or higher with p(O2) of 9.0x10-7 Torr or above contain mostly CuO contrasting to CuOQD grown at 800 K with p(O2) of ~7.0x10-7 Torr that contain primarily Cu2O. Furthermore, it is established that there is a strong interaction between the SrTiO3(001) surface and the first few monolayers of the CuOQD, which induces the formation of Cu(II). However, this interaction is mitigated with increasing thickness of CuOQD resulting in the exclusive formation of Cu2O in the topmost layers. The influence of the SrTiO3(001) substrate on the formation of CuOQD can be reduced by modifying the substrate surface using chemical treatment and/or energetic Au2? ion-beam irradiation, since the substrate effect results from the reaction between the substrate oxygen and the copper atoms from the CuOQD. Examination of the photochemical properties of these CuOQD shows that prolonged soft x-ray irradiation under vacuum reduces Cu(II), which is present as a minor impurity in the CuOQD.