Sulfated zirconia has received considerable attention as a potential solid acid catalyst in recent years. In this paper, the preparation and properties of acid catalysts obtained by grafting ziconia with atomic precision on MCM-41 mesoporous silica were studied. TEM and potential titration characterizations revealed that ZrO2/MCM-41 with monolayer coverage can be obtained using this grafting technique. Sulfated ZrO2/MCM-41 exhibits improved thermal stability than that of bulk sulfated zirconia, as evidenced by temperature programmed characterizations and XRD analysis. Temperature programmed reaction of isopropanol was used to evaluate the acidity of sulfated ZrO2/MCM-41. It was found that the acid strength of sulfated ZrO2/MCM-41 with monolayer coverage is weaker than bulk sulfated zirconia but stronger than SiO2-Al2O3, a common strong acid catalyst.
Revised: March 27, 2014 |
Published: June 1, 2007
Citation
Wang Y., K. Lee, S. Choi, J. Liu, L.Q. Wang, and C.H. Peden. 2007.Grafting Sulfated Zirconia on Mesoporous Silica.Green Chemistry 9, no. 6:540-544.PNNL-SA-52726.doi:10.1039/b614928f