June 25, 2007
Report

Evaluation of Exothermic Reactions from Bulk-Vitrification Melter Feeds Containing Cellulose

Abstract

PNNL has demonstrated that cellulose effectively reduces the amount of molten ionic salt during Bulk Vitrification of simulated Hanford Low Level Waste (LLW). To address concerns about the potential reactivity of cellulose-LLW, PNNL used thermogravimetric analysis, differential thermal analysis, and accelerating rate calorimetry to determine in these preliminary studies that these mixtures will support a self-sustaining reaction if heated to 110°C at adiabatic conditions. Additional testing is recommended.

Revised: February 25, 2010 | Published: June 25, 2007

Citation

Scheele R.D., B.K. McNamara, L.M. Bagaasen, S.J. Bos, A.E. Kozelisky, and P. Berry. 2007. Evaluation of Exothermic Reactions from Bulk-Vitrification Melter Feeds Containing Cellulose Richland, WA: Pacific Northwest National Laboratory.