PNNL

Abstract

Hydrologic properties that govern fluid flow through the sub-surface are porosity, permeability, relative permeability, fluid-fluid and fluid-solid interfacial areas, pore and particle size distributions, which may change due to dissolution/precipitation of minerals, fine particle release and capture, ion exchange and clay swelling. Provided here is a review on the change of hydrologic properties in sub-surface media due to chemical processes, and modeling of such changes. Precipitation and dissolution processes affecting the hydrologic properties, their kinetics and the effect of hydrodynamic factors on such processes were discussed. Precipitation in carbonaceous, siliceous, alkaline and acidic environments, and the role of dissolution and clay swelling in formation damage were reviewed. Changes in properties of unsaturated and fractured media were also discussed. Traditionally, different approaches were used to model various physico-chemical processes and their effect on the hydrologic properties. A detailed review of these methods, including the geochemical equilibrium and kinetic models, chemical divide pathway models, flow and transport models, precipitation/dissolution wave theory, network models, porosity and permeability reduction models, is presented. Recommendations are provided for the assessment of changes in the hydrologic properties of sub-surface media attributable to chemical reactions, and modeling flow and transport in their presence. Further, research needs on the changes in hydrologic properties and constitutive relationships among such properties in unsaturated media were identified.