PNNL

Abstract

Chalcogenide (arsenic sulfide) nanowires have been successfully synthesized from As2S3 under near-equilibrium conditions via evaporation–condensation process in evacuated glass ampoules. The as-synthesized nanowires were pure, nearly stoichiometric, and amorphous. The nanowires had diameters ranging from 40 to 140 nm and lengths up to a few millimeters. Distinct joints of the crisscrossing nanowires indicate potential for forming structural networks. They have been characterized using scanning electron microscopy (SEM), transmission electron microscopy (TEM), energy dispersive spectroscopy (EDS), Raman spectroscopy, and X-ray diffraction (XRD) to determine their structure, composition, and morphology. Selected area diffraction (SAD) in the TEM and XRD confirmed their amorphous nature. The As–S nanowires could make an ideal system for understanding the carrier transport and photonic properties in nanoscale for this family of materials (IV–V compounds). Chalcogenide nanowires show promise for integrated nanoelectronics and biophotonics.