May 13, 2025
Journal Article

From biomass to fuel blendstocks via catalytic fast pyrolysis and hydrotreating: an evaluation of carbon efficiency and fuel properties for three pathways

Abstract

Biomass was upgraded to fuel blendstocks via catalytic fast pyrolysis (CFP) followed by hydrotreating using three approaches: ex situ CFP with a zeolite catalyst (HZSM-5), ex situ CFP with a hydrodeoxygenation catalyst (Pt/TiO2) and co-fed hydrogen, and in situ CFP with a low-cost mixed metal oxide catalyst (red mud). Each approach was evaluated using a common pine feedstock and the same hydrotreating procedure. The oxygen contents in the CFP oils ranged from 17 to 28 wt% on a dry basis and the carbon efficiencies for the CFP processes were in the range of 28 to 38%. The residual oxygen was reduced to

Published: May 13, 2025

Citation

Iisa K., C. Mukarakate, R. French, F. Agblevor, D.M. Santosa, H. Wang, and N. Wilson, et al. 2023. From biomass to fuel blendstocks via catalytic fast pyrolysis and hydrotreating: an evaluation of carbon efficiency and fuel properties for three pathways. Energy and Fuels 37, no. 24:19653–19663. PNNL-SA-189900. doi:10.1021/acs.energyfuels.3c03239

Research topics