Chemical Engineer
Chemical Engineer

Biography

As a Chemical Engineer in the Geochemistry group at Pacific Northwest National Laboratory (PNNL), Dr. Trent R. Graham investigates the molecular-scale processes that govern nuclear waste chemistry and materials evolution. He uses multimodal spectroscopic approaches to probe solvated oxyanions, interfacial structures, and impurity-controlled reaction pathways, with an emphasis on nuclear magnetic resonance spectroscopy of quadrupolar nuclei. His current work incorporates muon spin rotation to probe solid-state impurity environments, radiation-induced reactivity, radical stabilization mechanisms, and electron-trapping processes.

Dr. Graham began his research at PNNL in 2017 as a PNNL-WSU Distinguished Graduate Research Program fellow. He earned both his PhD in Chemical Engineering and his BS in Biological Engineering from Washington State University.

Research Interest

  • Charge localization and radiation-driven reaction pathways
  • Coordination changes during mineral transformations
  • Reactivity and transport in concentrated electrolytes
  • Uncertainty quantification for interpreting spectroscopic and kinetic data

Disciplines and Skills

  • Solid- and liquid-state NMR methods, such as MQMAS and PFG NMR spectroscopy
  • X-ray diffraction and SEM/TEM for structural and interfacial analysis
  • Nanomaterial synthesis, including colloidal and core–shell nanoparticles
  • Stochastic Monte Carlo methods for propagating heteroscedastic uncertainty

Education

  • PhD, Chemical Engineering, Washington State University
  • BS, Biological Engineering, Washington State University

Awards and Recognitions

  • Outstanding Performance award, PNNL, 2020

Publications

See Dr. Graham's ORCiD profile for a continually updated list of his publications.

2025

  • Graham T.R., K. Ghandi, M. Prange, G. Schenter, L.M. Anovitz, J.A. LaVerne, and C.I. Pearce, et al. 2025. "Detecting impurity-specific effects on structure and radiolytic hydrogen production in aluminum hydroxide." Chemical Communications. doi:10.1039/D5CC05272F.
  • Graham T.R., M.P. Prange, X. Zhang, J.D. Bazak, N.M. Washton, K. Ghandi, G.K. Schenter, and C.I. Pearce, et al. 2025. "Localizing tetrahedral aluminum in nitrate-bearing gibbsite to constrain defect-impurity coupling." Inorganic Chemistry Frontiers. doi:10.1039/D5QI01703C.
  • Chen P., S. Wang, T.R. Graham, D. Song, X. Zhao, L. Liu, Z. Wang, C.I. Pearce, K.M. Rosso, and X. Zhang, et al. 2025. "Unraveling anion-specific inhibition and structural modulation of gibbsite crystallization: Implications for aluminum mobility in natural and engineered systems." ACS Applied Materials & Interfaces. doi:10.1021/acsami.5c17528.
  • Jaegers N.R., M.A. Derewinski, E.D. Walter, I.Z. Koleva, D. Boglaienko, D.J. Deka, G. Lee, T. Graham, L. Kovarik, and Y. Wang, et al. 2025. "Mechanistic insights into adsorptive and catalytic reactions from controllable distributions of metal cations (Pd, Pt, Ni, Cr, Cu) as [M-OH]+1/1Al or M+2/2Al in zeolites." Angewandte Chemie. doi:10.1002/ange.202516086.
  • Li X., Q. Guo, Y. Zhao, C. Qian, M. Pouvreau, T.R. Graham, P. Chen, L. Liu, C. Liu, B.A. Legg, et al. 2025. "Mineral dissolution by dimeric complexes." Proceedings of the National Academy of Sciences. doi:10.1073/pnas.2504109122.
  • Nienhuis E.T., S.T. Mergelsberg, T.R. Graham, A.R. Kennedy, C.I. Pearce, and J.G. Reynolds, et al. 2025. "Cesium exhibits different mesoscale segregation and ion pairing than lithium, sodium, or potassium in concentrated alkaline aqueous nitrite solutions." The Journal of Chemical Physics. doi:10.1063/5.0286139.
  • Felsted R.G., S.T. Mergelsberg, T.R. Graham, J.D. Bazak, C.I. Pearce, Z. Wang, and K.M. Rosso, et al. 2025. "Nonlinear scaling of water–ion interactions and dynamics in alkaline solutions." The Journal of Physical Chemistry Letters. doi:10.1021/acs.jpclett.5c02135.
  • Reynolds J.G., T.R. Graham, and C.I. Pearce, et al. 2025. "Zavitsas’ hydration model for electrolytes only stable in the presence of another: NaAl(OH)4 in aqueous NaOH solution." Fluid Phase Equilibria. doi:10.1016/j.fluid.2025.114392.
  • Graham T.R., A.R. Kennedy, J. Morton, J.G. Reynolds, and C.I. Pearce, et al. 2025. "Determining hexavalent chromium transport properties in alkaline nuclear waste using nuclear magnetic resonance spectroscopy." Communications Chemistry. doi:10.1038/s42004-025-01546-7.
  • Rajan B.P., S.T. Mergelsberg, M.E. Bowden, K.A. Peterson, S.D. Burton, G.M. Bowers, T.W. Wietsma, T.R. Graham, O. Qafoku, C.J. Thompson, et al. 2025. "Decreasing hygroscopicity slows forsterite carbonation under low-water conditions." Environmental Science & Technology. doi:10.1021/acs.est.5c01695.
  • Khivantsev K., H. Pham, M.H. Engelhard, H.A. Aleksandrov, L. Kovarik, M. Bowden, X.S. Li, J. Tian, I.Z. Koleva, I. Song, et al. 2025. "Transforming ceria into 2D clusters enhances catalytic activity." Nature. doi:10.1038/s41586-025-08684-x.
  • Liu J., Y. Wang, M. Pouvreau, J.-G. Wang, W. Liu, P. Chen, Y. Zhou, H.-W. Wang, T.R. Graham, and X. Guo, et al. 2025. "Direct observation of key aluminum hydroxide prenucleation oligomers for gibbsite nucleation and crystallization in sodium aluminate solution by liquid ToF-SIMS." Materials Today Chemistry. doi:10.1016/j.mtchem.2025.102596.
  • Granger-Jones J., T.R. Graham, C. Padilla Cintron, B. Robertson, S.C. Finkeldei, and J.A. Katalenich, et al. 2025. "Phase formation of γ-LiAlO2 via transformation of a layered double hydroxide (LDH) by internal gelation." Journal of Nuclear Materials. doi:10.1016/j.jnucmat.2024.155379.

2024

  • Scott S., K. Hobbs, T. Graham, N. Gajos, C. Berry, I. Anderson, and J. Williams, et al. 2024. "ICP-MS for analysis of lithium isotopic ratios in materials highly enriched in 7Li (CRADA 626) Final Report." Report. doi:10.2172/2500764.
  • Scott S.R., J. Williams, S. Mastromarino, N. Gajos, C. Berry, I. Anderson, S. Shen, T.R. Graham, C. Hexel, and J. Wimpenny, et al. 2024. "Round-robin analysis of highly depleted lithium for Generation IV nuclear reactor applications." Nuclear Engineering and Design. doi:10.1016/j.nucengdes.2024.113664.
  • Granger-Jones J., T.R. Graham, C. Padilla Cintron, B. Robertson, S.C. Finkeldei, and J.A. Katalenich, et al. 2024. "Phase formation of γ-LiAlO2 via transformation of a layered double hydroxide (LDH) by internal gelation." Journal of Nuclear Materials. doi:10.1016/j.jnucmat.2024.155379.
  • Wang H.-W., E.T. Nienhuis, T.R. Graham, M. Pouvreau, J.G. Reynolds, M. Bowden, G.K. Schenter, J.J. De Yoreo, K.M. Rosso, and C.I. Pearce, et al. 2024. "Resolving intermediates during the growth of aluminum deuteroxide (hydroxide) polymorphs in high chemical potential solutions." Communications Chemistry. doi:10.1038/s42004-024-01285-1.
  • Graham T.R., A.R. Kennedy, R.G. Felsted, R.A. Colina-Ruiz, E.T. Nienhuis, J.G. Reynolds, and C.I. Pearce, et al. 2024. "Multinuclear PFGSTE NMR description of 39K, 23Na, 7Li, and 1H specific activation energies governing diffusion in alkali nitrite solutions." Journal of Magnetic Resonance. doi:10.1016/j.jmr.2024.107707.
  • Felsted R.G., T.R. Graham, Y. Zhao, J.D. Bazak, E.T. Nienhuis, P.J. Pauzauskie, A.G. Joly, C.I. Pearce, Z. Wang, and K.M. Rosso, et al. 2024. "Anionic effects on concentrated aqueous lithium ion dynamics." The Journal of Physical Chemistry Letters. doi:10.1021/acs.jpclett.4c00585.
  • Zhao X., T.R. Guillen, T.R. Graham, P. Chen, Y. Zhao, S.T. Mergelsberg, Z. Zhu, Z. Wang, K.M. Rosso, and X. Guo, et al. 2024. "Incorporation of rare earth elements Sc, Y and La into gibbsite." Chemical Engineering Journal. doi:10.1016/j.cej.2024.149809.

2023

  • Wei Y., E.T. Nienhuis, S.T. Mergelsberg, T.R. Graham, Q. Guo, G.K. Schenter, C.I. Pearce, and A.E. Clark, et al. 2023. "Cation coordination polyhedra lead to multiple lengthscale organization in aqueous electrolytes." Chemical Communications. doi:10.1039/D3CC02416D.
  • Graham T.R., Y. Wei, E.D. Walter, E.T. Nienhuis, J. Chun, G.K. Schenter, K.M. Rosso, C.I. Pearce, and A.E. Clark, et al. 2023. "Tracking nitrite's deviation from Stokes–Einstein predictions with pulsed field gradient 15N NMR spectroscopy." Chemical Communications. doi:10.1039/D3CC04168A.
  • Graham T.R., B.N. Gartman, A. Bautista, L.E.I. Irwin, E.J. Shelby, D.L. Saunders, T.J. Johnson, M.K. Murphy, N. Uhnak, and A.M. Ritzmann, et al. 2023. "Spectroscopic features of dissolved iodine in pristine and gamma-irradiated nitric acid solutions." Journal of Molecular Liquids. doi:10.1016/j.molliq.2023.122631.
  • Loughran R.P., T. Hurley, A. Gładysiak, A. Chidambaram, K. Khivantsev, E.D. Walter, T.R. Graham, P. Reardon, J. Szanyi, and D.B. Fast, et al. 2023. "CO₂ capture from wet flue gas using a water-stable and cost-effective metal-organic framework." Cell Reports Physical Science. doi:10.1016/j.xcrp.2023.101470.
  • Nienhuis E.T., T.R. Graham, N.L. D’Annunzio, M.I. Kowalska, J.A. LaVerne, T.M. Orlando, J.G. Reynolds, D.M. Camaioni, K.M. Rosso, and C.I. Pearce, et al. 2023. "Cations impact radical reaction dynamics in concentrated multicomponent aqueous solutions." The Journal of Chemical Physics. doi:10.1063/5.0153132.
  • Graham T.R., M. Pouvreau, R. Gorniak, H.-W. Wang, E.T. Nienhuis, Q.R.S. Miller, J. Liu, M.P. Prange, G.K. Schenter, and C.I. Pearce, et al. 2023. "Disordered interfaces of alkaline aluminate salt hydrates provide glimpses of Al³⁺ coordination changes." Journal of Colloid and Interface Science. doi:10.1016/j.jcis.2023.01.003.
  • Hall G.B., E.L. Campbell, N. Bessen, T.R. Graham, H. Cho, M. RisenHuber, F.D. Heller, and G.J. Lumetta, et al. 2023. "Extraction of nitric acid and uranium with DEHiBA under high loading conditions." Inorganic Chemistry. doi:10.1021/acs.inorgchem.3c00288.
  • McCullough K.E., D.S. King, S.P. Chheda, M.S. Ferrandon, T.A. Goetjen, Z.H. Syed, T.R. Graham, N.M. Washton, O.K. Farha, and L. Gagliardi, et al. 2023. "High-throughput experimentation, theoretical modeling, and human intuition: Lessons learned in metal–organic-framework-supported catalyst design." ACS Central Science. doi:10.1021/acscentsci.2c01422.
  • Graham T.R., J. Castillo, S. Sinkov, A.V. Gelis, G.J. Lumetta, and H. Cho, et al. 2023. "Multiplicity of Th(IV) and U(VI) HEH[EHP] chelates at low temperatures from concentrated nitric acid extractions." Inorganic Chemistry. doi:10.1021/acs.inorgchem.2c03307.

2022

  • Graham T.R., J.Z. Hu, N.R. Jaegers, X. Zhang, C.I. Pearce, and K.M. Rosso, et al. 2022. "An amorphous sodium aluminate hydrate phase mediates aluminum coordination changes in highly alkaline sodium hydroxide solutions." Inorganic Chemistry Frontiers. doi:10.1039/D2QI01642G.
  • Graham T.R., E.T. Nienhuis, J.G. Reynolds, J. Marcial, J.S. Loring, K.M. Rosso, and C.I. Pearce, et al. 2022. "Sodium site occupancy and phosphate speciation in natrophosphate are invariant to changes in NaF and Na₃PO₄ concentration." Inorganic Chemistry Frontiers. doi:10.1039/D2QI00868H.
  • Nienhuis E.T., M. Pouvreau, T.R. Graham, M.P. Prange, K. Page, J.S. Loring, A.G. Stack, A.E. Clark, G.K. Schenter, and K.M. Rosso, et al. 2022. "Structure and reactivity of sodium aluminate complexes in alkaline solutions." Journal of Molecular Liquids. doi:10.1016/j.molliq.2022.120379.
  • Hall G., M. Prange, T. Graham, H. Cho, N. Govind, and G. Lumetta, et al. 2022. "Probing f-orbital covalency through the fold angles of transuranium dithiolene complexes." Report. doi:10.2172/1989490.
  • Reynolds J.G., T.R. Graham, and C.I. Pearce, et al. 2022. "Ion hydration controls self-diffusion in multicomponent aqueous electrolyte solutions of NaNO₂–NaOH–H₂O." Journal of Molecular Liquids. doi:10.1016/j.molliq.2022.119441.
  • Krzysko A.J., T.R. Graham, M. Dembowski, C. Beck, X. Zhang, K.M. Rosso, S.B. Clark, and C.I. Pearce, et al. 2022. "Isotopic substitution reveals the importance of aluminate diffusion dynamics in gibbsite (Al(OH)₃) crystallization from alkaline aqueous solution." ACS Earth and Space Chemistry. doi:10.1021/acsearthspacechem.1c00385.
  • Graham T.R., J. Chun, G.K. Schenter, X. Zhang, S.B. Clark, C.I. Pearce, and K.M. Rosso, et al. 2022. "27Al NMR diffusometry of Al₁₃ Keggin nanoclusters." Magnetic Resonance in Chemistry. doi:10.1002/mrc.5218.
  • Reynolds J.G., T.R. Graham, and C.I. Pearce, et al. 2022. "Extending Zavitsas’ hydration model to the thermodynamics of solute mixtures in water." Journal of Molecular Liquids. doi:10.1016/j.molliq.2021.118309.

2021

  • Mergelsberg S.T., M. Dembowski, M.E. Bowden, T.R. Graham, M. Prange, H.-W. Wang, X. Zhang, O. Qafoku, K.M. Rosso, and C.I. Pearce, et al. 2021. "Cluster defects in gibbsite nanoplates grown at acidic to neutral pH." Nanoscale. doi:10.1039/D1NR01615F.
  • Graham T.R., M. Dembowski, H.-W. Wang, S.T. Mergelsberg, E.T. Nienhuis, J.G. Reynolds, C.H. Delegard, Y. Wei, M. Snyder, and I.I. Leavy, et al. 2021. "Hydroxide promotes ion pairing in the NaNO₂–NaOH–H₂O system." Physical Chemistry Chemical Physics. doi:10.1039/D0CP04799F.
  • Dembowski M., J.S. Loring, M.E. Bowden, J.G. Reynolds, T.R. Graham, K.M. Rosso, and C.I. Pearce, et al. 2021. "The controlling role of atmosphere in dawsonite versus gibbsite precipitation from tetrahedral aluminate species." Dalton Transactions. doi:10.1039/D1DT02081A.
  • Han K.S., J.D. Bazak, Y. Chen, T.R. Graham, N.M. Washton, J.Z. Hu, V. Murugesan, and K.T. Mueller, et al. 2021. "Pulsed field gradient nuclear magnetic resonance and diffusion analysis in battery research." Chemistry of Materials. doi:10.1021/acs.chemmater.1c02891.
  • Prange M.P., T.R. Graham, R. Gorniak, M. Pouvreau, M. Dembowski, H.-W. Wang, L.L. Daemen, G.K. Schenter, M.E. Bowden, and E.T. Nienhuis, et al. 2021. "Theory-guided inelastic neutron scattering of crystalline alkaline aluminate salts bearing principal motifs of solution-state species." Inorganic Chemistry. doi:10.1021/acs.inorgchem.1c02006.
  • Zhang H., X. Zhang, T.R. Graham, C.I. Pearce, H. Hlushko, J.A. LaVerne, L. Liu, S. Wang, S. Zheng, and Y. Zhang, et al. 2021. "Crystallization and phase transformations of aluminum (oxy)hydroxide polymorphs in caustic aqueous solution." Inorganic Chemistry. doi:10.1021/acs.inorgchem.1c01111.
  • Mergelsberg S.T., S.L. Riechers, T.R. Graham, M.P. Prange, and S.N. Kerisit, et al. 2021. "Effect of Cd on the nucleation and transformation of amorphous calcium carbonate." Crystal Growth & Design. doi:10.1021/acs.cgd.1c00169.
  • Reynolds J.G., M. Dembowski, T.R. Graham, and C.I. Pearce, et al. 2021. "Nitrate and nitrite incompatibility with hydroxide ions in concentrated NaOH solutions: Implications for hydroxide and gibbsite reactivity in alkaline nuclear waste." Fluid Phase Equilibria. doi:10.1016/j.fluid.2020.112922.
  • Livo K., M. Prasad, and T.R. Graham, et al. 2021. "Quantification of dissolved O₂ in bulk aqueous solutions and porous media using NMR relaxometry." Scientific Reports. doi:10.1038/s41598-020-79441-5.

2020

  • Dembowski M., M.P. Prange, M. Pouvreau, T.R. Graham, M.E. Bowden, A. N’Diaye, G.K. Schenter, S.B. Clark, A.E. Clark, and K.M. Rosso, et al. 2020. "Inference of principal species in caustic aluminate solutions through solid-state spectroscopic characterization." Dalton Transactions. doi:10.1039/D0DT00229A.
  • Dembowski M., T.R. Graham, J.G. Reynolds, S.B. Clark, K.M. Rosso, and C.I. Pearce, et al. 2020. "Influence of soluble oligomeric aluminum on precipitation in the Al–KOH–H₂O system." Physical Chemistry Chemical Physics. doi:10.1039/D0CP04820H.
  • Dembowski M., M.M. Snyder, C. Delegard, J.G. Reynolds, T.R. Graham, H.-W. Wang, I.I. Leavy, S.R. Baum, O. Qafoku, and M.S. Fountain, et al. 2020. "Ion–ion interactions enhance aluminum solubility in alkaline suspensions of nano-gibbsite (α-Al(OH)₃) with sodium nitrite/nitrate." Physical Chemistry Chemical Physics. doi:10.1039/C9CP05856G.
  • Wang S., X. Zhang, T.R. Graham, H. Zhang, C.I. Pearce, Z. Wang, S.B. Clark, W. Jiang, and K.M. Rosso, et al. 2020. "Two-step route to size and shape controlled gibbsite nanoplates and the crystal growth mechanism." CrystEngComm. doi:10.1039/D0CE00114G.
  • Lu X., J.T. Reiser, B. Parruzot, T.R. Graham, and J. Vienna, et al. 2020. "Effects of Al:Si and (Al+Na):Si ratios on the properties of the international simple glass, part II: Structure." Journal of the American Ceramic Society. doi:10.1111/jace.17447.
  • Hammond-Pereira E., K. Bryant, T.R. Graham, and S.R. Saunders, et al. 2020. "Mesoporous silica-encapsulated gold core–shell nanoparticles for active solvent-free benzyl alcohol oxidation." Reaction Chemistry & Engineering. doi:10.1039/d0re00198h.
  • Banuelos J.L., S.R. Saunders, K.S. Han, T.R. Graham, and D.C. Cantu, et al. 2020. "Subtle changes in hydrogen bond orientation result in glassification of carbon capture solvents." Physical Chemistry Chemical Physics. doi:10.1039/d0cp03503c.
  • Huestis P.L., T.R. Graham, S.T. Mergelsberg, and J.A. LaVerne, et al. 2020. "Identification of radiolytically-active thermal transition phases in boehmite." Thermochimica Acta. doi:10.1016/j.tca.2020.178611.
  • Graham T.R., M. Dembowski, J.Z. Hu, N.R. Jaegers, X. Zhang, S.B. Clark, C.I. Pearce, and K.M. Rosso, et al. 2020. "Intermediate species in the crystallization of sodium aluminate hydroxy hydrates." The Journal of Physical Chemistry C. doi:10.1021/acs.jpcc.0c00205.
  • Placencia-Gómez E., S.N. Kerisit, H.S. Mehta, O. Qafoku, C.J. Thompson, T.R. Graham, E.S. Ilton, and J.S. Loring, et al. 2020. "Critical water coverage during forsterite carbonation in thin water films: Activating dissolution and mass transport." Environmental Science & Technology. doi:10.1021/acs.est.0c00897.
  • Graham T.R., R. Gorniak, M. Dembowski, X. Zhang, S.B. Clark, C.I. Pearce, A.E. Clark, and K.M. Rosso, et al. 2020. "Solid-state recrystallization pathways of sodium aluminate hydroxy hydrates." Inorganic Chemistry. doi:10.1021/acs.inorgchem.0c00258.
  • Krzysko A.J., E. Nakouzi, X. Zhang, A. Krzysko, J. Chun, G.K. Schenter, T.R. Graham, K.M. Rosso, and L.M. Anovitz, et al. 2020. "Correlating inter-particle forces and particle shape to shear-induced aggregation/fragmentation and rheology for dilute anisotropic particle suspensions: A complementary study via capillary rheometry and in-situ small and ultra-small angle X-ray scattering." Journal of Colloid and Interface Science. doi:10.1016/j.jcis.2020.04.016.

2019

  • Graham T.R., J.Z. Hu, X. Zhang, M. Dembowski, N.R. Jaegers, C. Wan, M. Bowden, A.S. Lipton, A.R. Felmy, and S.B. Clark, et al. 2019. "Unraveling gibbsite transformation pathways into LiAl–LDH in concentrated lithium hydroxide." Inorganic Chemistry. doi:10.1021/acs.inorgchem.9b02000.
  • Soltis J.A., T.R. Graham, X. Zhang, and G.A. Kimmel, et al. 2019. "Radiation-induced dissolution of a recalcitrant aluminum oxyhydroxide in liquid cell TEM." Microscopy and Microanalysis. doi:10.1017/s1431927619007827.
  • Wang H.-W., T.R. Graham, E. Mamontov, K. Page, A.G. Stack, and C.I. Pearce, et al. 2019. "Countercations control local specific bonding interactions and nucleation mechanisms in concentrated water-in-salt solutions." The Journal of Physical Chemistry Letters. doi:10.1021/acs.jpclett.9b01416.

2018

  • Zhang X., P.L. Huestis, C.I. Pearce, and K.M. Rosso, et al. 2018. "Boehmite and gibbsite nanoplates for the synthesis of advanced alumina products." ACS Applied Nano Materials. doi:10.1021/acsanm.8b01969.
  • Anovitz L.M., X. Zhang, J. Soltis, E. Nakouzi, A.J. Krzysko, J. Chun, G.K. Schenter, T.R. Graham, K.M. Rosso, and J.J. De Yoreo, et al. 2018. "Effects of ionic strength, salt, and pH on aggregation of boehmite nanocrystals: Tumbler small-angle neutron and X-ray scattering and imaging analysis." Langmuir. doi:10.1021/acs.langmuir.8b00865.
  • Graham T.R., D. Semrouni, E. Mamontov, A.J. Ramirez-Cuesta, K. Page, A. Clark, G.K. Schenter, C.I. Pearce, A.G. Stack, and H.-W. Wang, et al. 2018. "Coupled multimodal dynamics of hydrogen-containing ion networks in water-deficient, sodium hydroxide–aluminate solutions." The Journal of Physical Chemistry B. doi:10.1021/acs.jpcb.8b09375.
  • Graham T.R., K.S. Han, M. Dembowski, A.J. Krzysko, X. Zhang, J. Hu, S.B. Clark, A.E. Clark, G.K. Schenter, and C.I. Pearce, et al. 2018. "27Al pulsed field gradient, diffusion–NMR spectroscopy of solvation dynamics and ion pairing in alkaline aluminate solutions." The Journal of Physical Chemistry B. doi:10.1021/acs.jpcb.8b10145.
  • Graham T.R., M. Dembowski, E. Martínez-Báez, X. Zhang, S.B. Clark, C.I. Pearce, and K.M. Rosso, et al. 2018. "In situ 27Al NMR spectroscopy of aluminate in sodium hydroxide solutions above and below saturation with respect to gibbsite." Inorganic Chemistry. doi:10.1021/acs.inorgchem.8b00617.
  • Nakouzi E., J. Soltis, B. Legg, G.K. Schenter, X. Zhang, T.R. Graham, K.M. Rosso, L.M. Anovitz, J.J. De Yoreo, and J. Chun, et al. 2018. "Impact of solution chemistry and particle anisotropy on the collective dynamics of oriented aggregation." ACS Nano. doi:10.1021/acsnano.8b04909.
  • Zhang X., W. Cui, K. Page, T.R. Graham, K.M. Rosso, and Z. Wang, et al. 2018. "Size and morphology controlled synthesis of boehmite nanoplates and crystal growth mechanisms." Crystal Growth & Design. doi:10.1021/acs.cgd.8b00394.

2017

  • Graham T.R., J. Hu, X. Zhang, N.R. Jaegers, K.M. Rosso, and S.B. Clark, et al. 2017. "Transitions in Al coordination during gibbsite crystallization using high-field 27Al and 23Na MAS NMR spectroscopy." The Journal of Physical Chemistry C. doi:10.1021/acs.jpcc.7b10424.
  • Zhang X., X. Zhang, T.R. Graham, K.M. Rosso, and W. Chen, et al. 2017. "Fast synthesis of gibbsite nanoplates and process optimization using Box–Behnken experimental design." Crystal Growth & Design. doi:10.1021/acs.cgd.7b01400.