July 28, 2017
News Release

Cool MOFs

Nanomaterials show promise for chillers

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MOFs, sometimes visually likened to the classic Tinkertoy wooden play construction kits, are made up of metal ions clusters connected by organic linker molecules or bridging-ligands whose geometry and connectivity dictate the structure of the MOFs. By adjusting linker geometry and other characteristics, the size, shape and internal surface properties of MOFs can be optimized for targeted specific uses, such as cooling systems.

About 15 percent of all energy usage in the U.S. goes toward cooling. New research from the Department of Energy's Pacific Northwest National Laboratory may ultimately help lower energy consumption for air conditioning by engineering tiny porous materials to hold onto a large amount of refrigerant gases.

The high attachment of this gas — an environmentally friendly fluorocarbon called R134 and water — to nanomaterials called metal organic frameworks hold promise for their use in adsorbent cooling systems that a can be powered by waste heat.

In a paper just published in the Journal of the American Chemical Society, PNNL found that this refrigerant adhered to the high open metal centers of the MOF. Results also indicate that researchers could likely engineer the pores of the material to enhance the amount of the refrigerant loading even further. And the small nanostructure of the MOF and its higher sorption rate means the cooling systems can be made much smaller and, therefore, more efficient and economically viable.

One exciting development turns out to be the potential to quickly identify refrigerant leaks both in adsorbent chillers and traditional air conditioning systems.The MOF material in the study is highly sensitive to infrared light, which shows even extreme low concentrations of water and refrigerant as a visual peak on a spectrum. This may provide an easy way to detect hidden coolant leaks, which cause a reduction in cooling and a higher use of energy.

Learn more in this highlight.

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About PNNL

Pacific Northwest National Laboratory draws on its distinguishing strengths in chemistry, Earth sciences, biology and data science to advance scientific knowledge and address challenges in energy resiliency and national security. Founded in 1965, PNNL is operated by Battelle and supported by the Office of Science of the U.S. Department of Energy. The Office of Science is the single largest supporter of basic research in the physical sciences in the United States and is working to address some of the most pressing challenges of our time. For more information, visit the DOE Office of Science website. For more information on PNNL, visit PNNL's News Center. Follow us on Twitter, Facebook, LinkedIn and Instagram.

Published: July 28, 2017