A rechargeable battery stores readily convertible chemical energy to operate a variety of devices such as mobile phones, laptop computers, and electric automobiles, etc. A battery generally consists of four components, i.e., a cathode, an anode, a separator and electrolytes. The properties of these components jointly determine the safety, the lifetime, and the electrochemical performance, include but not limited to the power density and the charge, recharge time/rate associated with a battery system. Extensive amount of research is thus dedicated to understand the physical and chemical properties associated with each of the four components aimed at developing new generations of battery systems with greatly enhanced safety and electrochemical performance while at significantly reduced cost for large scale applications. Advanced characterization tools are prerequisite to fundamentally understand battery materials. Considering that some of the key electrochemical processes can only exist under in situ conditions, thus, can only be captured under a working battery conditions when electric wires are attached and current and voltage applied, in situ detection is critical. NMR, a non-invasive and atomic specific tool, is capable of detecting all phases, including crystalline, amorphous, liquid and gaseous phases simultaneously and is ideal for in situ detection on a working battery system. Ex situ NMR on the other hand can provide more detailed molecular or structural information on stable species with better spectral resolution and sensitivity. The combination of in situ and ex situ NMR, thus, offers a powerful tool for investigating the detailed electrochemistry in batteries.
Revised: August 23, 2019 |
Published: November 21, 2018
Citation
Hu J.Z., N.R. Jaegers, M.Y. Hu, and K.T. Mueller. 2018.In Situ and Ex Situ NMR for Battery Research.Journal of Physics: Condensed Matter 30, no. 46:Article No. 463001.PNNL-SA-134425.doi:10.1088/1361-648X/aae5b8