May 1, 2020
Journal Article

Phyllosilicate mineral dissolution upon alkaline treatment under aerobic and anaerobic conditions

Abstract

The dissolution of phyllosilicate minerals exposed to high-pH environments has been studied to determine the influence of alkaline treatments and variable redox conditions on clay dissolution and the potential formation of new phases via incongruent dissolution phenomena. The present study focused on the dissolution of phyllosilicate minerals (illite, muscovite, and montmorillonite) under anaerobic and aerobic conditions using comparative solutions (sodium hydroxide and ammonium hydroxide) at similar ionic strength in the presence and absence of oxygen. Our batch data show that there is a rapid decrease in aluminum dissolution (

Revised: July 19, 2020 | Published: May 1, 2020

Citation

Di Pietro S., H.P. Emerson, Y. Katsenovich, N. Qafoku, and J.E. Szecsody. 2020. Phyllosilicate mineral dissolution upon alkaline treatment under aerobic and anaerobic conditions. Applied Clay Science 189. PNNL-SA-149956. doi:10.1016/j.clay.2020.105520