A Li-air battery could potentially provide three to five times higher energy density/specific energy than conventional batteries, thus enable the driving range of an electric vehicle comparable to a gasoline vehicle. However, making Li-air batteries rechargeable presents significant challenges, mostly related with materials. Herein, we discuss the key factors that influence the rechargeability of Li-air batteries with a focus on nonaqueous system. The status and materials challenges for nonaqueous rechargeable Li-air batteries are reviewed. These include electrolytes, cathode (electocatalysts), lithium metal anodes, and oxygen-selective membranes (oxygen supply from air). The perspective of rechargeable Li-air batteries is provided.
Revised: April 19, 2013 |
Published: February 25, 2013
Citation
Shao Y., F. Ding, J. Xiao, J. Zhang, W. Xu, S. Park, and J. Zhang, et al. 2013.Making Li-air batteries rechargeable: material challenges.Advanced Functional Materials 23, no. 8:987-1004.PNNL-SA-85805.doi:10.1002/adfm.201200688