Intrinsic affinities of alkali cations for 15-crown-5 and 18-crown-6: bond dissociation energies of gas-phase M+-crown ether complexes

January 20, 1999

Journal Article

Intrinsic affinities of alkali cations for 15-crown-5 and 18-crown-6: bond dissociation energies of gas-phase M+-crown ether complexes

Abstract

Bond dissociation energies (BDEs) of M+[c-(C2H4O)5] and M+[c-(C2H4O6] for M = Na, K, Rb, and Cs re reported.

Revised: April 18, 2000 | Published: January 20, 1999

Citation

More M.B., D. Ray, P.B. Armentrout, and P.B. Armentrout. 1999. Intrinsic affinities of alkali cations for 15-crown-5 and 18-crown-6: bond dissociation energies of gas-phase M+-crown ether complexes. Journal of the American Chemical Society 121, no. 2:417-423. PNNL-SA-30177.