January 19, 2018
Report

Gas Generation Testing of Spherical Resorcinol-Formaldehyde (sRF) Resin

Abstract

This report describes gas generation testing of the spherical resorcinol-formaldehyde (sRF) resin that was conducted to support the technology maturation of the LAWPS facility. The current safety basis for the LAWPS facility is based primarily on two studies that had limited or inconclusive data sets. The two studies indicated a 40% increase in hydrogen generation rate of water (as predicted by the Hu model) with sRF resin over water alone. However, the previous studies did not test the range of conditions (process fluids and temperatures) that are expected in the LAWPS facility. Additionally, the previous studies did not obtain replicate test results or comparable liquid-only control samples. All of the testing described in this report, conducted with water, 0.45M nitric acid, and waste simulants with and without sRF resin, returned hydrogen generation rates that are within the current safety basis for the facility of 1.4 times the Hu model output for water.

Revised: February 16, 2018 | Published: January 19, 2018

Citation

Colburn H.A., S.A. Bryan, D.M. Camaioni, L.A. Mahoney, and S.R. Adami. 2018. Gas Generation Testing of Spherical Resorcinol-Formaldehyde (sRF) Resin Richland, WA: Pacific Northwest National Laboratory.