PNNL

Abstract

This study details thermal reactions between glasses, common minerals, and Trinitite post-detonation material with the fluorinating agent nitrogen trifluoride (NF3). The ultimate goal of our investigation is to develop a relatively rapid method for the effective separation of bomb components from complex matrices resulting from a nuclear explosion. Trinitite samples, silicate minerals (quartz; plagioclase and microcline), amorphous SiO2, calcite, a natural glass (obsidian), and two synthetic glasses were characterized extensively before and after the fluorination to fully understand the effects of the NF3 thermal treatment. Samples were reacted with NF3 using a combined thermogravimetric (TG) differential thermal analysis (DTA) unit, as well as in a stainless steel bomb reactor connected to a fluorination line. Subsequent to the NF3 treatment, samples were imaged by scanning electron microscopy in order to document changes in grain size and morphology.