Deposition of silane-based self-assembled monolayers onto mesoporous ceramic substrates has been found to be substantially faster from supercritical fluids than from typical condensed phase solutions. In addition, the monolayers so prepared display higher silane population density, fewer defects and greater stability than do those prepared via standard solution methods. A mechanistic rationale for the pressure-induced rate enhancement and reduced defect density is presented.
Revised: March 11, 2002 |
Published: December 25, 2001
Citation
Zemanian T.S., G.E. Fryxell, J. Liu, S.V. Mattigod, J.A. Franz, and Z. Nie. 2001.Deposition of Self-Assembled Monolayers in Mesoporous Silica from Supercritical Fluids.Langmuir 17, no. 26:8172-8177.PNNL-SA-34809.