PNNL

Abstract

Pumping of fluids is universally performed by using mechanical or thermal compressors. We demonstrate for the first time a new solid-state molecular pumping mechanism induced by switching the adsorption affinity for a gas through polarization of a chromophore under an applied electric field. Mass spectrometry was used to trace refrigerant gas (difluoromethane) uptake on a chromophore-coated capacitor under applied voltage and subsequent desorption when the voltage and electrode polarization was removed showing an exchange capacity of 0.11 mol of refrigerant per liter of chromophore. Calorimetry confirmed a reversible enthalpy change of 9 Kcal/mol in the polarization-induced sorption-desorption process. The present work establishes the principle and feasibility of non-mechanical molecular pumping, which can be exploited for refrigeration, catalysis, gas separation, among many other potential applications.