PNNL

Abstract

The kinetics of matrix dissolution and alkali-exchange for a series of sodium aluminosilicate glass compositions was determined at constant temperature and solution pH(D) under conditions of silica-saturation. Steady state release rate for sodium was 10 to 50 times faster than the rate of matrix dissolution, demonstrating that alkali exchange is an important long-term reaction mechanism that must be considered when modeling systems near saturation with respect to dissolved glass components. Sodium release rates were 30% slower in D2O compared to rates in H2O; but matrix dissolution rates were unaffected. These results are consistent with rupture of the O-H bond as the rate-limiting reaction in Na+-H+ exchange whereas matrix dissolution is controlled by OH- or H2O catalyzed hydrolysis of Si-O-Si and Si-O-Al bonds. Changes in Na exchange rate with increasing Al2O3 content could not be reconciled with changes in the number of non-bridging oxygen (NBO) sites in the glass alone. A simple model was used to estimate a structural energy barrier for alkali ion exchange using Na-O bond length and coordination as measured by Na K-edge XANES spectroscopy, and binding energy shifts for Si-O-Na sites measured by XPS. The energy barrier was calculated to increase from 34 kJ/mol for Na2O?2SiO2 glass to 50 kJ/mol for a glass containing 15 mol% Al2O3, consistent with stronger bonding of Na on NBO sites and increasing mechanical stiffness of the glass network with increasing Al content. The calculated ion-exchange enthalpies were then used to calculate Na ion exchange rates as a function of glass composition. Agreement between the calculated and measured Na ion exchange rates was excellent.