In this paper, we demonstrate the utility of single-particle analysis to investigate the chemistry of isolated, individual particles of atmospheric relevance such as NaCl, sea salt, CaCO3, and SiO2. A variety of state-of-th-art scanning electron microscopy techniques, including environmental scanning electon microscopy and computer-controlled scanning electron microscopy/energy-dispersive X-ray analysis, were utilized for monitoring and quantifying phase transitions of individual particles, morphology, and compositional changes of individual particles as they react with nitric acid.
Revised: April 7, 2011 |
Published: October 1, 2003
Citation
Krueger B.J., V.H. Grassian, M.J. Iedema, J.P. Cowin, and A. Laskin. 2003.Probing Heterogeneous Chemistry of Individual Atmospheric Particles Using Scanning Electron Microscopy and Energy-Dispersive X-ray Analysis.Analytical Chemistry 75, no. 19:5170-5179.PNNL-SA-39709.