PNNL

Abstract

The formation of ternary complexes between lanthanide ions [Nd(III) or Eu(III)], octyl(phenyl)-N,N-diisobutyl-carbamoylmethylphosphine oxide (CMPO), and bis-(2-ethylhexyl)phosphoric acid (HDEHP) was probed by liquid-liquid extraction and spectroscopic techniques. Equilibrium modeling of data for the extraction of Nd(III) or Eu(III) from lactic acid media into n-dodecane solutions of CMPO and HDEHP indicates the predominant extracted species are of the type [Ln(AHA)2(A)] and [Ln(CMPO)(AHA)2(A)], where Ln = Nd or Eu and A represents the DEHP anion. FTIR (for both Eu and Nd) and visible spectrophotometry (in the case of Nd) indicate the formation of the [Ln(CMPO)(A)3] complexes when CMPO is added to n-dodecane solutions of the LnA3 compounds. Both techniques indicate a stronger propensity of CMPO to complex Nd(III) versus Eu(III).