January 18, 2012
Report

Iron Phosphate Glass-Containing Hanford Waste Simulant

Abstract

Resolution of the nation’s high-level tank waste legacy requires the design, construction, and operation of large and technically complex one-of-a-kind processing waste treatment and vitrification facilities. While the ultimate limits for waste loading and melter efficiency have yet to be defined or realized, significant reductions in glass volumes for disposal and mission life may be possible with advancements in melter technologies and/or glass formulations. This test report describes the experimental results from a small-scale test using the research-scale melter (RSM) at Pacific Northwest National Laboratory (PNNL) to demonstrate the viability of iron-phosphate-based glass with a selected waste composition that is high in sulfate (4.37 wt% SO3). The primary objective of the test was to develop data to support a cost-benefit analysis related to the implementation of phosphate-based glasses for Hanford low-activity waste (LAW) and/or other high-level waste streams within the U.S. Department of Energy complex. The testing was performed by PNNL and supported by Idaho National Laboratory, Savannah River National Laboratory, Missouri University of Science and Technology, and Mo-Sci Corporation.

Revised: February 1, 2012 | Published: January 18, 2012

Citation

Sevigny G.J., M.L. Kimura, C.M. Fischer, M.J. Schweiger, C.P. Rodriguez, D. Kim, and B.J. Riley. 2012. Iron Phosphate Glass-Containing Hanford Waste Simulant Richland, WA: Pacific Northwest National Laboratory.