The chiral 3D MOFs resulted from the packing of chiral 1D SBBs were studied. It was demonstrated that the final packing pattern is dependent on the dimension of SBB’s. In addition, we were able to identify a new plywood-like network from ligand 2H2 exhibiting an unprecedented six-way chiral helical packing motif, which can be added on the list of invariant rod packings.
Revised: October 11, 2011 |
Published: July 20, 2011
Citation
Shin S.M., D. Moon, K.S. Jeong, J. Kim, P.K. Thallapally, and N. Jeong. 2011.Homochiral 3D Metal-Organic Frameworks from Chiral 1D Rods: 6 – Way Helical Packing.Chemical Communications 47, no. 33:9402-9404.PNNL-SA-80092.doi:10.1039/C1CC12908B