The jet-cooled spectrum of pentafluoroethane (C2HF5) has been recorded between 1100 and 1325 cm-1 at a resolution of 0.0022 cm-1. A rotational temperature of approximately 10 K was achieved by expanding 50 Torr of C2HF5 in 500 Torr of helium. Transitions belonging to five different fundamental vibrations have been assigned and fit to a Watson Hamiltonian: the m3 band at 1309.880494(189) cm-1, m4 at 1200.734645(67) cm-1, m5 at 1142.78147(33) cm-1, m13 at 1223.334098(115) cm-1, and m14 at 1147.394185(163) cm-1. The fit of the m4 band has an rms deviation of 0.000436 cm-1 compared to the uncertainty in the experimental line position of 0.0002 cm-1. Satisfactory fits were achieved for the other four bands (m3, m5, m13, m14) at this cold temperature, with most of the centrifugal distortion constants fixed at the ground state values. Joint fits with previous work were attempted for the m4 and m13, successfully in the former case and unsuccessfully in the latter.
Revised: April 27, 2011 |
Published: February 1, 2011
Citation
Goss L.M., W.R. Hess, T.A. Blake, and R.L. Sams. 2011.The High-Resolution, Jet-cooled Infrared Spectrum of Pentafluoroethane.Journal of Molecular Spectroscopy 265, no. 2:81-85.PNNL-SA-79075.doi:10.1016/j.jms.2010.11.002