The catalytic conversion of cyclohexanol on zeolite HBEA in hot liquid water leads to dehydration as well as alkylation products. A novel micro autoclave suitable for application in MAS NMR at high temperatures and pressures is developed and successfully applied to obtain new insight into the mechanistic pathway leading to an understanding of the reactions under selected experimental conditions.
Revised: August 12, 2014 |
Published: January 7, 2014
Citation
Vjunov A., M.Y. Hu, J. Feng, D.M. Camaioni, D. Mei, J.Z. Hu, and C. Zhao, et al. 2014.Following Solid-Acid-Catalyzed Reactions by MAS NMR Spectroscopy in Liquid Phase -Zeolite-Catalyzed Conversion of Cyclohexanol in Water.Angewandte Chemie International Edition 53, no. 2:479-482.PNNL-SA-96916.doi:10.1002/anie.201306673