February 9, 2010
Journal Article

Bulk Migration of Ni/NiO in Ni-YSZ during Reducing Conditions

Abstract

Understanding the migration of Ni/NiO in Ni-YSZ can potentially help to design a better solid oxide fuel cell (SOFC) anode. We have observed that extensive hydrogen reduction and methane steam reforming of Ni-YSZ caused bulk migration of Ni/NiO to at least ~ 5 µm deeper from the Ni-YSZ surface. No significant bulk migration effects were detected after simple thermal treatments in non-reducing/non-reforming environment. Surface analysis of a single zirconia grain in the first 10-20 nm region from annealed, hydrogen reduced and methane steam reformed Ni-YSZ shows Ni-enriched surface supporting earlier claims of Ni exsolution. 3D-EBSD analysis of thermally treated sample before exposing it to reducing and reforming environment indicated mixed NiO/YSZ phase with some porosity and random grain orientation. The surface analysis and mapping were carried out using ToF-SIMS and AES whereas EDS maps on FIB sliced areas on Ni-YSZ were utilized for the bulk analysis. The results provide additional information related to complex reactions occurring in SOFC during internal reforming conditions.

Revised: April 1, 2010 | Published: February 9, 2010

Citation

Saraf L.V., D.R. Baer, A.S. Lea, Z. Zhu, J.J. Strohm, S.D. Sitzman, and D.L. King. 2010. Bulk Migration of Ni/NiO in Ni-YSZ during Reducing Conditions. Journal of the Electrochemical Society 157, no. 4:B463-B469. PNNL-SA-64179. doi:10.1149/1.3298442