Staff information

Biography

Dr. Bruce Kay and his colleagues are applying and extending molecular-beam surface scattering techniques to ice surfaces to examine the chemical kinetics and reaction dynamics of molecular processes occurring both on the surface and within the bulk of amorphous and crystalline ice films. We use these "chemically tailored" nanoscale films as model systems to elucidate the mechanistic details of the complex physiochemical processes that take place in aqueous solutions, deeply super-cooled liquids, astrophysical dust and comets, and at the aqueous-mineral geochemical interface. In related experiments, we are examining hydrophobic and hydrophilic interactions between water and various other materials using thermal desorption and surface spectroscopic techniques to probe interphase transport and phase separation. Elucidation of these processes will further our understanding of solvation and reactions in multi-phase, multi-component solutions and in determining reaction mechanisms in heterogeneous systems. These molecular-level studies are germane to Department of Energy programs in environmental restoration, waste processing, and contaminant fate and transport.

We are also using molecular beam scattering instrumentation to study physisorption and chemisorption on oxide surfaces. Recently, we have shown that physisorption of weakly bound gases can be used to titrate small concentrations of surface defects and to determine their binding energies on magnesium oxide(100). Currently, we are also engaged in adsorption studies on the surfaces of nanoporous thin MgO films. This work was initiated by our discovery of the deposition angle dependent porosity of amorphous solid water films grown under ballistic deposition (BD) conditions. We have found that the MgO films created under reactive BD conditions are composed of a tilted array of porous nanoscale crystalline filaments with high porosity (~ 90%) and high-surface area (~ 1000 m2/g). These films have chemical binding sites analogous to those on MgO(100). However the fraction of chemically active, high energy binding sites is greatly enhanced on the nanoporous film. This unique collection of properties makes these materials attractive candidates for chemical applications such as sensors and heterogeneous catalysts.

Education and Credentials

• University of Illinois, Chicago, IL: B. S., in Chemistry, Mathematics (minor) (1976) with Honors and Highest Distinction
• University of Colorado, Boulder, CO: Ph. D., in Chemical Physics (1982) Advisor: Prof. A. W. Castleman Jr. Dissertation: "Dynamics, Energetics and Structure of Hydrogen-Bonded Clusters: Elucidating the Transition from the Gaseous to the Condensed State"

Affiliations and Professional Service

• Fellow of the American Chemical Society (2010)
• Fellow of the American Association for the Advancement of Science (AAAS, 2005)
• Fellow of the American Vacuum Society (AVS, 2000)
• Fellow of the American Physical Society (APS, 2000)
• Elected to Sigma Xi (1980)

Awards and Recognitions

• Editorial Board, Journal of Chemical Physics (2009-2011)
• British Vacuum Council John Yarwood Medal (1991)
• ACS Undergraduate Award in Analytical Chemistry (1976)
• Visiting Professor of Chemical Physics,University of Liverpool, UK, 2006-present
• Editioral Advisory Board, Journal of Physical Chemistry (2005-2007)
• International Advisory Board, Academica Sinica Institute for
• Atomic and Molecular Science, Taiwan (2004-2007)
• Elected to a leadership role in the American Chemical Society
• Physical Chemistry Division serving a five year rotation as vice chair elect through past chairman during the period 2003 through 2008
• Co-Chair of the Dynamics and Kinetics working group at the DOE-BES Workshop on Nanoscience and Catalysis, Gaithersburg MD, May 14-16, 2002
• Editorial Board of the Review Journal, Progress in Surface Science (2000-2006)
• Vice Chairman (1999) and Chairman (2001), Gordon Conference on Dynamics at Surfaces

PNNL Publications

2023

• Kringle L.M., B.D. Kay, and G.A. Kimmel. 2023. "Dynamic Heterogeneity and Kovacs' Memory Effects in Supercooled Water." Journal of Physical Chemistry B 127, no. 17:3919-3930. PNNL-SA-182629. doi:10.1021/acs.jpcb.3c01465
• Kringle L.M., B.D. Kay, and G.A. Kimmel. 2023. "Structural relaxation of water during rapid cooling from ambient temperatures." The Journal of Chemical Physics 159, no. 6:Art. No. 064509. PNNL-SA-184979. doi:10.1063/5.0157046

2022

• Kringle L.M., W.A. Thornley, B.D. Kay, and G.A. Kimmel. 2022. "Isotope effects on the structural transformation and relaxation of deeply supercooled water." The Journal of Chemical Physics 156, no. 8:Art. No. 084501. PNNL-SA-168415. doi:10.1063/5.0078796
• Sharp M., C.J. Lee, M. Mahapatra, R.S. Smith, B.D. Kay, and Z. Dohnalek. 2022. "Preparation and characterization of model homotopic catalysts: Rh adatoms, nanoparticles, and mixed oxide surfaces on Fe3O4(001)." Journal of Physical Chemistry C 126, no. 34:14448-14459. PNNL-SA-173190. doi:10.1021/acs.jpcc.2c03426

2021

• Kringle L.M., W.A. Thornley, B.D. Kay, and G.A. Kimmel. 2021. "Structural relaxation and crystallization in supercooled water from 170 to 260 K." Proceedings of the National Academy of Sciences (PNAS) 118, no. 14:e2022884118. PNNL-SA-158074. doi:10.1073/pnas.2022884118
• Lee C.J., M. Sharp, R.S. Smith, B.D. Kay, and Z. Dohnalek. 2021. "Adsorption of ethane, ethene, and ethyne on reconstructed Fe3O4(001)." Surface Science 714. PNNL-SA-161889. doi:10.1016/j.susc.2021.121932

2019

• Doudin N.M., S.F. Yuk, M.D. Marcinkowski, M. Nguyen, J. Liu, Y. Wang, and Z. Novotny, et al. 2019. "Understanding Heterolytic H2 Cleavage and Water-Assisted Hydrogen Spillover on Fe3O4(001)-Supported Single Palladium Atoms." ACS Catalysis 9, no. 9:7876-7887. PNNL-SA-141193. doi:10.1021/acscatal.9b01425

2016

• Kim B., Z. Dohnalek, J. Szanyi, B.D. Kay, and Y. Kim. 2016. "Temperature-programmed Desorption Study of NO Reactions on Rutile TiO2(110)-1x1." Surface Science 652. PNNL-SA-114302. doi:10.1016/j.susc.2016.01.032
• Yu X., Z. Zhang, C. Yang, F. Bebensee, S. Heibler, A. Nefedov, and M. Tang, et al. 2016. "Interaction of Formaldehyde with the Rutile TiO2(110) Surface: A Combined Experimental and Theoretical Study." Journal of Physical Chemistry C 120, no. 23:12626-12636. PNNL-SA-116863. doi:10.1021/acs.jpcc.6b03689

2015

• Kim B., B.D. Kay, Z. Dohnalek, and Y. Kim. 2015. "Ammonia formation from NO reaction with surface hydroxyls on rutile TiO2 (110) - 1x1." Journal of Physical Chemistry C 119, no. 2:1130-1135. PNNL-SA-106365. doi:10.1021/jp5109619

2014

• Fang Z., Z. Li, M.S. Kelley, B.D. Kay, S. Li, J.M. Hennigan, and R.J. Rousseau, et al. 2014. "Oxidation, Reduction, and Condensation of Alcohols over (MO3)3 (M=Mo, W) Nanoclusters." Journal of Physical Chemistry C 118, no. 39:22620-22634. PNNL-SA-103803. doi:10.1021/jp5072132
• Kim B., Z. Li, B.D. Kay, Z. Dohnalek, and Y. Kim. 2014. "Low-Temperature Desorption of N2O from NO on Rutile TiO2(110)-1x1." Journal of Physical Chemistry C 118, no. 18:9544-9550. PNNL-SA-100646. doi:10.1021/jp501179y
• Lercher J.A., A.M. Appel, T. Autrey, R.M. Bullock, D.M. Camaioni, H.M. Cho, and D.A. Dixon, et al. 2014. "Multifunctional Catalysts to Synthesize and Utilize Energy Carriers." In Frontiers at the Interface between Homogeneous and Heterogeneous Catalysis, II, 207-219. Washington, District Of Columbia:U.S. Department of Energy, Office of Science. PNNL-SA-103068.
• Li Z., Z. Fang, M.S. Kelley, B.D. Kay, R.J. Rousseau, Z. Dohnalek, and D.A. Dixon. 2014. "Ethanol Conversion on Cyclic (MO3)3 (M = Mo, W) Clusters." Journal of Physical Chemistry C 118, no. 9:4869-4877. PNNL-SA-98029. doi:10.1021/jp500255f
• Molinero V., and B.D. Kay. 2014. "Preface: Special Topic on Interfacial and Confined Water." Journal of Chemical Physics 141, no. 18:Article No. 18C101. PNNL-SA-106166. doi:10.1063/1.4900822
• Rousseau R.J., D.A. Dixon, B.D. Kay, and Z. Dohnalek. 2014. "Dehydration, Dehydrogenation, and Condensation of Alcohols on Supported Oxide Catalysts Based on Cyclic (WO3)3 and (MoO3)3 Clusters." Chemical Society Reviews 43, no. 22:7664-7680. PNNL-SA-99875. doi:10.1039/c3cs60445d

2013

• Acharya D.P., Y. Yoon, Z. Li, Z. Zhang, X. Lin, R. Mu, and L. Chen, et al. 2013. "Site-Specific Imaging of Elemental Steps in Dehydration of Diols on TiO2(110)." ACS Nano 7, no. 11:10414-10423. PNNL-SA-98207. doi:10.1021/nn404934q
• Li Z., B.D. Kay, and Z. Dohnalek. 2013. "Dehydration and Dehydrogenation of Ethylene Glycol on Rutile TiO2(110)." Physical Chemistry Chemical Physics. PCCP 15, no. 29:12180-12186. PNNL-SA-93701. doi:10.1039/c3cp50687h
• Lin X., Z. Wang, I. Lyubinetsky, B.D. Kay, and Z. Dohnalek. 2013. "Interaction of CO2 with Oxygen Adatoms on Rutile TiO2(110)." Physical Chemistry Chemical Physics. PCCP 15, no. 17:6190-6195. PNNL-SA-91922. doi:10.1039/C3CP44040K

2012

• Flaherty D.W., N.T. Hahn, R.A. May, S.P. Berglund, Y. Lin, K.J. Stevenson, and K.J. Stevenson, et al. 2012. "Reactive Ballistic Deposition of Nanostructured Model Materials for Electrochemical Energy Conversion and Storage." Accounts of Chemical Research 45, no. 3:434-443. PNNL-SA-80939. doi:10.1021/ar200164u
• Kim B., Z. Li, B.D. Kay, Z. Dohnalek, and Y. Kim. 2012. "The effect of oxygen vacancies on the binding interactions of NH3 with rutile TiO2(110) -1x1." Physical Chemistry Chemical Physics. PCCP 14, no. 43:15060-15065. PNNL-SA-89318. doi:10.1039/C2CP42754K
• Kim B., Z. Li, B.D. Kay, Z. Dohnalek, and Y. Kim. 2012. "Unexpected Nondissociative Binding of N2O on Oxygen Vacancies on a Rutile TiO2(110)-1x1." Journal of Physical Chemistry C 116, no. 1:1145-1150. PNNL-SA-83511. doi:10.1021/jp210636j
• Li S., Z. Li, Z. Zhang, B.D. Kay, R.J. Rousseau, and Z. Dohnalek. 2012. "Preparation, Characterization, and Catalytic Properties of Tungsten Trioxide Cyclic Trimers on FeO(111)/Pt(111)." Journal of Physical Chemistry C 116, no. 1:908-916. PNNL-SA-82959. doi:10.1021/jp2093324
• Li Z., B. Smid, Y. Kim, V. Matolin, B.D. Kay, R.J. Rousseau, and Z. Dohnalek. 2012. "Alcohol Dehydration on Monooxo W=O and Dioxo O=W=O Species." The Journal of Physical Chemistry Letters 3, no. 16:2168-2172. PNNL-SA-88790. doi:10.1021/jz300885v
• Lin X., Y. Yoon, N.G. Petrik, Z. Li, Z. Wang, V.A. Glezakou, and B.D. Kay, et al. 2012. "Structure and Dynamics of CO2 on Rutile TiO2(110)-1x1." Journal of Physical Chemistry C 116, no. 50:26322-26334. PNNL-SA-89052. doi:10.1021/jp308061j
• Zhang Z., Y. Yoon, X. Lin, D.P. Acharya, B.D. Kay, R.J. Rousseau, and Z. Dohnalek. 2012. "OH Group Dynamics of 1, 3-propanediol on TiO2(110)." The Journal of Physical Chemistry Letters 3, no. 22:3257-3263. PNNL-SA-90595. doi:10.1021/jz301412m

2011

• Li Z., Z. Zhang, B.D. Kay, and Z. Dohnalek. 2011. "Polymerization of Formaldehyde and Acetaldehyde on Ordered (WO3)3 Films on Pt(111)." Journal of Physical Chemistry C 115, no. 19:9692-9700. PNNL-SA-78252. doi:10.1021/jp202169x

2010

• Kim J., B.D. Kay, and Z. Dohnalek. 2010. "Formaldehyde Polymerization on (WO3)3/TiO2(110) Model Catalyst." Journal of Physical Chemistry C 114, no. 40:17017-17022. PNNL-SA-71733.

2009

• Kim Y., Z. Zhang, G.S. Parkinson, S. Li, B.D. Kay, and Z. Dohnalek. 2009. "Reactivity of FeO(111)/Pt(111)with Alcohols." Journal of Physical Chemistry C 113, no. 46:20020-20028. PNNL-SA-67864.
• Kim Y.K., Z. Dohnalek, B.D. Kay, and R.J. Rousseau. 2009. "Competitive Oxidation and Reduction of Aliphatic Alcohols over (WO3)3 Clusters." Journal of Physical Chemistry C 113, no. 22:9721-9730. PNNL-SA-63868.
• Zhang Z., R.J. Rousseau, J. Gong, B.D. Kay, and Z. Dohnalek. 2009. "Imaging Hindered Rotations of Alkoxy Species on TiO2(110)." Journal of the American Chemical Society 131, no. 49:17926-17932. PNNL-SA-68160.

2008

• Dohnalek Z., J. Kim, and B.D. Kay. 2008. "Understanding How Surface Morphology and Hydrogen Dissolution Influence Ethylene Hydrogenation on Palladium." Journal of Physical Chemistry C 112, no. 40:15796-15801. PNNL-SA-51220. doi:10.1021/jp803880x
• Kim Y., B.D. Kay, J.M. White, and Z. Dohnalek. 2008. "2-Propanol Dehydration on TiO2(110): The Effect of Bridge-Bonded Oxygen Vacancy Blocking." Surface Science 602, no. 2:511-516. PNNL-SA-57162. doi:10.1016/j.susc.2007.10.049
• Kim Y., R.J. Rousseau, B.D. Kay, J.M. White, and Z. Dohnalek. 2008. "Catalytic Dehydration of 2-Propanol on (WO3)3 Clusters on TiO2(110)." Journal of the American Chemical Society 130, no. 15:5059-5061. PNNL-SA-58711. doi:10.1021/ja800730g
• Li S., Z. Zhang, D. Sheppard, B.D. Kay, J.M. White, Y. Du, and I. Lyubinetsky, et al. 2008. "Intrinsic Diffusion of Hydrogen on Rutile TiO2(110)." Journal of the American Chemical Society 130, no. 28:9080-9088. PNNL-SA-58537. doi:10.1021/ja8012825
• Zhang Z., R.J. Rousseau, J. Gong, S. Li, B.D. Kay, Q. Ge, and Z. Dohnalek. 2008. "Vacancy Assisted Diffusion of Alkoxy Species on Rutile TiO2(110)." Physical Review Letters 101, no. 15:156103. PNNL-SA-59664. doi:10.1103/PhysRevLett.101.156103

2007

• Bondarchuk O., Y. Kim, J.M. White, J. Kim, B.D. Kay, and Z. Dohnalek. 2007. "Surface Chemistry of 2-Propanol on TiO2(110): Low and High Temperature Dehydration, Isotope Effects, and Influence of Local Surface Structure." Journal of Physical Chemistry C 111, no. 29:1105-11067. PNNL-SA-54619. doi:10.1021/jp072298m
• Dixon D.A., Z. Dohnalek, M.S. Gutowski, J. Hu, E. Iglesia, B.D. Kay, and J. Liu, et al. 2007. "Early Transition Metal Oxides as Catalysts: Crossing Scales from Clusters to Single Crystals to Functioning Materials." In Frontiers in Catalysis Science. Meeting of the Catalysis and Chemical Transformations Program Chemical Sciences, Geosciences and Biosciences Division, Office of Basic Energy Sciences, U.S. Department of Energy Rockville, MD May 23-26, 2004, 389-392. Washington, District Of Columbia:Department of Energy. PNNL-SA-54459.
• Flaherty D.W., Z. Dohnalek, A. Dohnalkova, B.W. Arey, D.E. McCready, N. Ponnusany, and C. Mullins, et al. 2007. "Reactive Ballistic Deposition of Porous TiO2 Films: Growth and Characterization." Journal of Physical Chemistry C 111, no. 12:4765-4773. PNNL-SA-52580. doi:10.1021/jp067641m
• Kim J., O. Bondarchuk, B.D. Kay, J.M. White, and Z. Dohnalek. 2007. "Preparation and Characterization of Monodispersed WO3 Nanoclusters on TiO2(110)." Catalysis Today 120, no. 2:186-195. PNNL-SA-50486. doi:10.1016/j.cattod.2006.07.050
• Kim Y., B.D. Kay, J.M. White, and Z. Dohnalek. 2007. "Alcohol Chemistry on Rutile TiO2(110): The Influence of Alkyl Substituents on Reactivity and Selectivity." Journal of Physical Chemistry C 111, no. 49:18236-18242. PNNL-SA-56213. doi:10.1021/jp075608+
• Kim Y., B.D. Kay, J.M. White, and Z. Dohnalek. 2007. "Inductive Effect of Alkyl Chains on Alcohol Dehydration at Bridge-Bonded Oxygen Vacancies of TiO2(110)." Catalysis Letters 119, no. 1-2:1-4. PNNL-SA-54909. doi:10.1007/s10562-007-9199-1
• Kimmel G.A., N.G. Petrik, Z. Dohnalek, and B.D. Kay. 2007. "Crystalline Ice Growth on Pt(111) and Pd(111): Nonwetting Growth on a Hydrophobic Water Monolayer." Journal of Chemical Physics 126, no. 11:Art. No. 114702. PNNL-SA-51889.
• Zhang Z., O. Bondarchuk, B.D. Kay, J.M. White, and Z. Dohnalek. 2007. "Direct Visualization of 2-Butanol Adsorption and Dissociation on TiO2(110)." Journal of Physical Chemistry C 111, no. 7:3021-3027. PNNL-SA-51362. doi:10.1021/jp067461c
• Zhang Z., Q. Ge, S. Li, B.D. Kay, J.M. White, and Z. Dohnalek. 2007. "Imaging Intrinsic Diffusion of Bridge-Bonded Oxygen Vacancies on TiO2(110)." Physical Review Letters 99, no. 12:paper #126105. PNNL-SA-53640. doi:10.1103/PhysRevLett.99.126105

2006

• Bondarchuk O., X. Huang, J. Kim, B.D. Kay, L.S. Wang, J.M. White, and Z. Dohnalek. 2006. "Formation of Monodisperse (WO3)3 Clusters on Ti02(110)." Angewandte Chemie International Edition 45, no. 29:4786-4789. PNNL-SA-47808. doi:10.1002/anie.200600837
• Dohnalek Z., J. Kim, and B.D. Kay. 2006. "Growth of Epitaxial Thin Pd(111) Films on Pt(111) and Oxygen-Terminated FeO(111) Surfaces." Surface Science 600, no. 17:3461-3471. PNNL-SA-47863. doi:10.1016/j.susc.2006.06.036
• Dohnalek Z., J. Kim, O.A. Bondarchuk, J.M. White, and B.D. Kay. 2006. "Physisorption of N2, O2, and CO on Fully Oxidized TiO2(110)." Journal of Physical Chemistry B 110, no. 12:6229-6235. PNNL-SA-47092. doi:10.1021/jp0564905
• Kimmel G.A., N.G. Petrik, Z. Dohnalek, and B.D. Kay. 2006. "Layer-by-Layer Growth of Thin Amorphous Solid Water Films on Pt(111) and Pd(111)." Journal of Chemical Physics 125, no. 4:044713-1 - 044713-12. PNNL-SA-48867. doi:10.1063/1.2218844
• Tait S.L., Z. Dohnalek, C.T. Campbell, and B.D. Kay. 2006. "n-alkanes on Pt(111) and on C(0001)/Pt(111): Chain Length Dependence of Kinetic Desorption Parameters." Journal of Chemical Physics 125, no. 23:Art. No. 234308. PNNL-SA-52516. doi:10.1063/1.2400235
• Zhang Z., O. Bondarchuk, B.D. Kay, J.M. White, and Z. Dohnalek. 2006. "Imaging Water Dissociation on TiO2(110): Evidence for Inequivalent Geminate OH Groups." Journal of Physical Chemistry B 110, no. 43:21840-21845. PNNL-SA-50470. doi:10.1021/jp063619h
• Zhang Z., O. Bondarchuk, J.M. White, B.D. Kay, and Z. Dohnalek. 2006. "Imaging Adsorbate O-H Bond Cleavage: Methanol on TiO2(110)." Journal of the American Chemical Society 128, no. 13:4198-4199. PNNL-SA-47892. doi:10.1021/ja058466a

2005

• Batista E., P. Ayotte, A. Bilic, B.D. Kay, and H. Jonsson. 2005. "What Determines the Sticking Probability of Water Molecules on Ice?." Physical Review Letters. PNNL-SA-47750. doi:10.1103/PhysRevLett.95.223201
• Dixon D.A., Z. Dohnalek, M.S. Gutowski, J.Z. Hu, E. Iglesia, B.D. Kay, and J. Liu, et al. 2005. "Early Transition Metal Oxides as Catalysts: Crossing Scales from Clusters to Single Crystals to Functioning Materials." In Frontiers in Catalysis Science: Proceedings of the 12th DOE/BES Heterogeneous Catalysis & Surface Science Meeting, 389-392. Upton, New York:Frontiers in Catalysis Science. PNNL-SA-42058.
• Garrett B.C., D.A. Dixon, D.M. Camaioni, D.M. Chipman, M.A. Johnson, C.D. Jonah, and G.A. Kimmel, et al. 2005. "Role of Water in Electron-Initiated Processes and Radical Chemistry: Issues and Scientific Advances." Chemical Reviews 105, no. 1:355-389. PNNL-SA-42304. doi:10.1021/cr030453x
• Hornekaer L., A. Baurichter, V.V. Petrunin, A.C. Luntz, B.D. Kay, and A. Al-Halabi. 2005. "Influence of Surface Morphology on D-2 Desorption Kinetics from Amorphous Solid Water." Journal of Chemical Physics 122, no. 12:124701-1 - 11. PNNL-SA-45193. doi:10.1063/1.1874934
• Kim J., Z. Dohnalek, and B.D. Kay. 2005. "Cryogenic CO2 Formation on Oxidized Gold Clusters Synthesized via Reactive Layer Assisted Deposition." Journal of the American Chemical Society 127, no. 42:14592-93. PNNL-SA-46190.
• Kim J., Z. Dohnalek, and B.D. Kay. 2005. "Structural Characterization of Nanoporous Pd Films Grown Via Ballistic Deposition." Surface Science 586, no. 1-3:137-145. PNNL-SA-43826.
• Kimmel G.A., N.G. Petrik, Z. Dohnalek, and B.D. Kay. 2005. "Crystalline Ice Growth on Pt(111): Observation of a Hydrophobic Water Monolayer." Physical Review Letters 95, no. 16:166102. PNNL-SA-45342.
• Tait S.L., Z. Dohnalek, C. Campbell, and B.D. Kay. 2005. "Methane Adsorption and Dissociation and Oxygen Adsorption and Reaction with CO on Pd Nanoparticles on MgO(100) and on Pd(111)." Surface Science 591, no. 1-3:90-107. PNNL-SA-45238.
• Tait S.L., Z. Dohnalek, C.T. Campbell, and B.D. Kay. 2005. "n-Alkanes on MgO(100). I: Coverage-Dependent Desorption Kinetics of n-Butane." Journal of Chemical Physics 122, no. 16:4707 (9 pages). PNNL-SA-43247.
• Tait S.L., Z. Dohnalek, C.T. Campbell, and B.D. Kay. 2005. "n-Alkanes on MgO(100). II. Chain Length Dependence of Kinetic Desorption Parameters for Small n-Alkanes." Journal of Chemical Physics 122, no. 16:4708 (13 pages). PNNL-SA-43228.

2004

• Kim J., Z. Dohnalek, J.M. White, and B.D. Kay. 2004. "Reactive Growth of Nanoscale MgO Films by Mg Atom Deposition onto O2 Multilayers." Journal of Physical Chemistry B 108, no. 31:11666-11671. PNNL-SA-40944.

2003

• Kimmel G.A., M. Persson, Z. Dohnalek, and B.D. Kay. 2003. "Temperature Independent Physisorption Kinetics and Adsorbate Layer Compression for Ar Adsorbed on Pt (111)." Journal of Chemical Physics 119, no. 13:6776-6783. PNNL-SA-37480.

1999

• Peden C.H., G.S. Herman, I.Z. Ismagilov, B.D. Kay, M.A. Henderson, Y.J. Kim, and S.A. Chambers. 1999. "Model Catalyst Studies with Single Crystals and Epitaxial Thin Oxide Films." Catalysis Today 51, no. 3-4:513-519. PNNL-SA-29513.

1994

• Jackson B.E., M. Perrson, and B.D. Kay. 1994. "Quantum Mechanical Study of H(g)+CI-Au(111): Eley-Rideal Mechanism." Journal of Chemical Physics 100, no. 10:7687-7695. PNL-SA-25843. doi:10.1063/1.466862